Electron transfer tuning for persulfate activation via the radical and non-radical pathways with biochar mediator.

Electron mediator-based in-situ chemical oxidation (ISCO) offers a novel strategy for groundwater remediation due to diverse reaction pathways. However, distinguishing and further tuning the reaction pathway remains challenging. Herein, biochar as an electron mediator targeted active peroxysulphate (PDS) via the radical or non-radical pathway.

[Transformation Behavior and Environmental Effects of Microplastics in Soil-groundwater].

As an emerging pollutant, microplastics exist widely in the environment. At present, the research on microplastics mainly focuses on the atmosphere, ocean, river, and other environmental media. Soil-groundwater has become a significant sink and has received increased interest in recent years.

Evaluation of the immobilized enzymes function in soil remediation following polycyclic aromatic hydrocarbon contamination.

The bioremediation of polycyclic aromatic hydrocarbon (PAHs) from soil utilizing microorganisms, enzymes, microbial consortiums, strains, etc. has attracted a lot of interest due to the environmentally friendly, and cost-effective features. Enzymes can efficiently break down PAHs in soil by hydroxylating the benzene ring, breaking the C-C bond, and catalyze the hydroxylation of a variety of benzene ring compounds via single-electron transfer oxidation.

Spatial distribution and migration characteristics of heavy metals at an abandoned industrial site in the Southwest of China.

The rapid acceleration of global industrialization has rendered heavy metal contamination at abandoned industrial sites a severe challenge, particularly in geologically complex and fragile karst regions of Southwest China, posing significant threats to ecosystems and public health. However, existing research lacks a comprehensive understanding of the spatial distribution and migration mechanisms of heavy metals in this region. In this study, 523 soil samples and 30 groundwater samples were collected, and the pollution levels were systematically assessed using the Geo-Accumulation Index, Single Pollution Index, and Nemerow Integrated Pollution Index.

Enhanced biocatalytic laccase production using agricultural waste in solid-state fermentation by Aspergillus oryzae for p-chlorophenol degradation.

Agricultural residues are one of the most cost-effective and readily accessible carbon resources for producing commercially significant enzymes. Several enzymes have been used in different industries like pharmaceuticals, foods, textiles, and dyes that can be generated by various species of microbes found in waste from agriculture. The current research investigated laccase production by Aspergillus oryzae utilizing agricultural wastes.

Uptake and translocation of cadmium and trace metals in common rice varieties at different growth stages.

Rice (Oryza sativa) is an important nutritional grain for the majority of Asian countries, but it is also a major source of cadmium (Cd) accumulation. A pot experiment was carried out to investigate the Cd uptake and translocation of high Cd (IR-50) and low Cd (White Ponni) rice cultivars in Cd-contaminated soils. The findings revealed that Cd impacts on rice development and growth differed depending on rice cultivars.

Evaluation of groundwater quality with multi-source pollution based on source identification and health risks.

Groundwater is a crucial water supply source in Chengdu City, western China, a region experiencing significant water scarcity. The sources of inorganic pollutants in groundwater and their potential health risks are of great concern. In this study, based on 156 groundwater samples collected in 2021 in the study area were analyzed for hydrochemical characterization and controlling factors.

Quality evaluation and health risk assessment of karst groundwater in Southwest China.

Groundwater in karst regions is of immense value due to its vital support for regional ecosystems and residents' livelihoods. However, it is simultaneously threatened by multi-source pollution from agricultural non-point sources, industrial and domestic point sources, and mining activities. This study focuses on the Guangxi of China, which features typical karst topography, aiming to thoroughly assess the groundwater quality and related health risks in Guangxi, especially identifying the impacts of various key pollution sources on the groundwater environment.

Enhanced Arsenate Immobilization by Kaolinite via Heterogeneous Pathways during Ferrous Iron Oxidation.

Clay minerals are ubiquitous in subsurface environments and have long been recognized as having a limited or negligible impact on the fate of arsenic (As) due to their negatively charged surfaces. Here, we demonstrate the significant role of kaolinite (Kln), a pervasive clay mineral, in enhancing As(V) immobilization during ferrous iron (Fe(II)) oxidation at near-neutral pH. Our results showed that Fe(II) oxidation alone was not capable of immobilizing As(V) at relatively low Fe/As molar ratios (≤2) due to the generation of Fe(III)-As(V) nanocolloids that could still migrate easily as truly dissolved As did.

Progress in enhancing the remediation performance of microbial fuel cells for contaminated groundwater.

Microbial fuel cells (MFCs) have become more prevalent in groundwater remediation due to their capacity for power generation, removal of pollution, ease of assembly, and low secondary contamination. It is currently being evaluated for practical application in an effort to eliminate groundwater pollution. However, a considerable majority of research was conducted in laboratories.

Bibliometric analysis and systematic review of electrochemical methods for environmental remediation.

Electrochemical methods are increasingly favored for remediating polluted environments due to their environmental compatibility and reagent-saving features. However, a comprehensive understanding of recent progress, mechanisms, and trends in these methods is currently lacking. Web of Science (WoS) databases were utilized for searching the primary data to understand the knowledge structure and research trends of publications on electrochemical methods and to unveil certain hotspots and future trends of electrochemical methods research.

Critical Role of Mineral Fe(IV) Formation in Low Hydroxyl Radical Yields during Fe(II)-Bearing Clay Mineral Oxygenation.

In subsurface environments, Fe(II)-bearing clay minerals can serve as crucial electron sources for O activation, leading to the sequential production of O, HO, and OH. However, the observed OH yields are notably low, and the underlying mechanism remains unclear. In this study, we investigated the production of oxidants from oxygenation of reduced Fe-rich nontronite NAu-2 and Fe-poor montmorillonite SWy-3.

Studies on the transfer effect of aged polyethylene microplastics in soil-plant system.

The widespread use of polyethylene (PE) agricultural films has led to a large accumulation of microplastics in soil, and the environmental effects of microplastics on soil-plants have received increasing attention. In the actual soil environment, microplastics undergo significant changes in their physicochemical properties due to aging, accompanied by complex ecological and environmental effects. However, the quantitative understanding of the environmental effects of microplastic aging in soil-plant systems is still unclear.

Influencing factors and controlled release kinetics of HO from PVP-coated calcium peroxide NPs for groundwater remediation.

Calcium peroxide nanoparticles (nCP) as a versatile and safe solid source of hydrogen peroxide (HO) receive substantial attention from researchers as a potential groundwater remediation reagent. In this study, we synthesized polyvinylpyrrolidone-coated calcium peroxide nanoparticles (PVP@nCP-PVP) to control the release rate of HO and modulate pH fluctuation simultaneously. The PVP@nCP-PVP is fully characterized and the HO releasing kinetics and mechanisms are investigated.

Abiogenic silicon: Interaction with potentially toxic elements and its ecological significance in soil and plant systems.

Abiogenic silicon (Si), though deemed a quasi-nutrient, remains largely inaccessible to plants due to its prevalence within mineral ores. Nevertheless, the influence of Si extends across a spectrum of pivotal plant processes. Si emerges as a versatile boon for plants, conferring a plethora of advantages.

A new quantitative insight: Interaction of polyethylene microplastics with soil - microbiome - crop.

In this study, the interaction between primary/secondary PE MPs and soil - microbiome - crop complex system and PE MPs enrichment behavior in crops were studied by using the self-developed quantitative characterization method of Eu-MPs and in situ zymography. The results demonstrated for the first time the enrichment effect of micron-sized PE (> 10 µm) in crops, manifested as roots>leaves>stems. Primary PE MPs significantly increased soil TN, TC, SOM and β-glu activity and inhibited Phos activity.

As(III) removal from aqueous solutions using simultaneous oxidation and adsorption process by hierarchically magnetic flower-like FeO@C-dot@MnO nanocomposite.

In the present study, a magnetic flower-like FeO@C-dot@MnO nanocomposite was synthesized by hydrothermal method and applied for As(III) removal by oxidation and adsorption process. Individual property of the entire material (i.e.

Effects of different fertilization methods on Lolium multiflorum Lam. growth and bacterial community in waste slag.

Waste slag has low nutrient content, so it has insufficient nutrient cycling and transformation in the soil ecosystem. There are few studies on the application of oligotrophic phosphate-solubilizing bacteria and phosphate (P) fertilizer to improve the properties of waste slags. In this study, three oligotrophic bacterial strains with P solubilizing activity, namely, Bacillus subtilis 2C (7.

Molecular structure-dependent contribution of reactive species to organic pollutant degradation using nanosheet BiFeO activated peroxymonosulfate.

Iron-based catalysts have attracted increasing attention in heterogeneous activation of peroxymonosulfate (PMS). However, the activity of most iron-based heterogenous catalysts is not satisfactory for practical application and the proposed activation mechanisms of PMS by iron-based heterogenous catalyst vary case by case. This study prepared BiFeO (BFO) nanosheet with super high activity toward PMS, which was comparable to its homogeneous counterpart at pH 3.

Multifunctional Nano-Realgar Hydrogel for Enhanced Glioblastoma Synergistic Chemotherapy and Radiotherapy: A New Paradigm of an Old Drug.

Purpose: Realgar, as a kind of traditional mineral Chinese medicine, can inhibit multiple solid tumor growth and serve as an adjuvant drug in cancer therapy. However, the extremely low solubility and poor body absorptive capacity limit its application in clinical medicine. To overcome this therapeutic hurdle, realgar can here be fabricated into a nano-realgar hydrogel with enhanced chemotherapy and radiotherapy (RT) ability.

Nutrients in the rhizosphere: A meta-analysis of content, availability, and influencing factors.

Nutrient deficiency in most terrestrial ecosystems constrains global primary productivity. Rhizosphere nutrient availability directly regulates plant growth and is influenced by many factors, including soil properties, plant characteristics and climate. A quantitatively comprehensive understanding of the role of these factors in modulating rhizosphere nutrient availability remains largely unknown.

Impact of ZnO nanoparticles on soil lead bioavailability and microbial properties.

In the present study, we investigated the responses of microbial respiration and community structure, enzyme activity and DTPA-extractable Pb within 60 days of incubation in soils treated with Pb and nano-ZnO. The results showed that when the concentration of nano-ZnO exceeded 10 mg/kg, the concentration of DTPA-extractable Pb significantly decreased by 10.6%-21.

Improving methane production from algal sludge anaerobic fermentation by peroxydisulfate (PDS) pretreatment.

This study investigated the potential of improving methane production from algal sludge anaerobic digestion by peroxydisulfate (PDS) pretreatment. The results show that with PDS dosage at 0.02 g PDS/g algal sludge TSS, PDS added system has highest accumulative methane production after 60 days fermentation.