Making nanostructured metal oxides intertwined with graphitic carbon materials is critically important to construct hybrid supercapacitors with high-performance, cost-affordable, and free-standing 1D hybrid electrode material and is of foremost importance to responding positively to the impending energy crisis. Fine-tuned nano-sized ZIF-67 particles of 5 - 25 nm width (OZIF-67) are achieved using oleylamine-involved synthesis and are seeded into fibrous poly-PAN-PVP. Porous N-doped carbon nanofibers impregnated with OZIF-67-derived CoO (oz-CoO-PNCNF) are obtained by calcining the electrospun polymer.
View Article and Find Full Text PDFManufacturing high-performance and cost-affordable non-metallic, electroactive 1D carbon material for energy storage and hydrogen evolution reaction (HER) is of foremost importance to respond positively to the impending energy crisis. Porous N-doped carbon nanofiber (PNCNF) is successfully synthesized by electrospinning, using selenium nanoparticles as a sacrificial template (where Se is reutilized for ZIF-67 selenization as a bi-process, and the surface of PNCNF is modified with poly(3,4-ethylenedioxythiophene) (PNCNT/PEDOT) by electropolymerization. The prepared materials are found ideal for energy storage (supercapacitor) and electrocatalysis (HER).
View Article and Find Full Text PDFIEEE Trans Biomed Circuits Syst
August 2024
Opioid tampering and diversion pose a serious problem for hospital patients with potentially life-threatening consequences. The ongoing opioid crisis has resulted in medications used for pain management and anesthesia, such as fentanyl and morphine, being stolen, substituted with a different substance, and abused. This work aims to mitigate tampering and diversion through analytical verification of the administered drug before it enters the patient.
View Article and Find Full Text PDFViral pandemic diseases have disruptive global consequences leading to millions of deaths and a severe impact on the global economy. Inadequate preventative protocols have led to an overwhelming demand for intensive care leading to uncontrollable burdens and even breakdown of healthcare sectors across many countries. The rapid detection of viral disease helps in the understanding of the relevant intricacies, helping to tackle infection with improved guidelines.
View Article and Find Full Text PDFWe are aiming to develop an electrochemical microcatheter sensor for the detection and real-time continuous monitoring of propofol (PPF), which is an anesthetic drug majorly used during medical treatment. This proposed microcatheter-based sensing strategy meets the challenge of real-time periodic and continuous monitoring of propofol by using d-TiCT-rGO-chi-modified carbon paste microcatheter sensor transducer. The sensing methodology relies on voltammetry and chronoamperometry transduction methods.
View Article and Find Full Text PDFEnvironmental toxic pollutants and pathogens that enter the ecosystem are major global issues. Detection of these toxic chemicals/pollutants and the diagnosis of a disease is a first step in efficiently controlling their contamination and spread, respectively. Various analytical techniques are available to detect and determine toxic chemicals/pathogens, including liquid chromatography, HPLC, mass spectroscopy, and enzyme-linked immunosorbent assays.
View Article and Find Full Text PDFCancer is one of the major public health issues in the world. It has become the second leading cause of death, with approximately 75% of cancer deaths transpiring in low- or middle-income countries. It causes a heavy global economic cost estimated at more than a trillion dollars per year.
View Article and Find Full Text PDFThe design and development of biosensors, analytical devices used to detect various analytes in different matrices, has emerged. Biosensors indicate a biorecognition element with a physicochemical analyzer or detector, i.e.
View Article and Find Full Text PDFThis review (with 163 refs) covers the recent developments of nanomaterial-based optical and electrochemical sensors for mycotoxins. The review starts with a brief discussion on occurrence, distribution, toxicity of mycotoxins and the legislations in monitoring their levels. It further outlines the research methods, various recognition matrices and the strategies involved in the development of highly sensitive and selective sensor systems.
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