Synthesis, Characterization, and Biological Activity of New 4'-Functionalized Bis-Terpyridine Ruthenium(II) Complexes: Anti-Inflammatory Activity Advances.

Ruthenium complexes incorporating 2,2' : 6',2''-terpyridine ligands have emerged as promising candidates due to their versatile biological activities including DNA-binding, anti-inflammatory, antimicrobial, and anticancer properties. In this study, three new 4'-functionalized bis(terpyridine) Ru(II) complexes were synthesized. These complexes feature one ligand as 4-(2,2' : 6',2''-terpyridine-4'-yl) benzoic acid and the second ligand as either 4'-(2-thienyl)-2,2' : 6',2''-terpyridine, 4'-(3,4-dimethoxyphenyl)-2,2' : 6',2''-terpyridine, or 4'-(4-dimethylaminophenyl)-2,2' : 6',2''-terpyridine.

Thieno[2,3-c]isoquinolines: A novel chemotype of antiproliferative agents inducing cellular apoptosis while targeting the G2/M phase and Tubulin.

In the era of modern synthetic methodology and advanced bio-evaluation techniques and considering the notorious history of hepatocellular carcinoma (HCC), hopeful expectations regarding novel bioactive chemotypes have grown dramatically. Among the widely versatile motifs in drug discovery studies are isoquinoline and thieno[2,3-b]pyridine. Herein, the molecular merging of both motifs evoked thieno[2,3-c]isoquinoline as a novel antiproliferative chemotype being hardly studied against HCC.

Electrophoretic deposition of hydroxyapatite/chitosan nanocomposites: the effect of dispersing agents on the coating properties.

In this study, electrophoretic deposition (EPD) was used for the coating on titanium (Ti) substrate with a composite of hydroxyapatite (HA)-chitosan (CS) in the presence of dispersing agents such as polyvinyl butyral (PVB), polyethylene glycol (PEG), and triethanolamine (TEA). The materials were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), zeta potential, and Fourier transform infrared (FT-IR) spectroscopy. The addition of PVB, PEG, and TEA agents improved the development of Ti coating during the EPD process.

Correction: A cerium-based MOFzyme with multi-enzyme-like activity for the disruption and inhibition of fungal recolonization.

Correction for 'A cerium-based MOFzyme with multi-enzyme-like activity for the disruption and inhibition of fungal recolonization' by Hani Nasser Abdelhamid et al., J. Mater.

Comparison between Benzothiadizole-Thiophene- and Benzothiadizole-Furan-Based D-A-π-A Dyes Applied in Dye-Sensitized Solar Cells: Experimental and Theoretical Insights.

Three novel donor-acceptor-π-acceptor-type compounds (WS5, WS6, and WS7) were synthesized and investigated in dye-sensitized solar cells (DSSCs) exploring the effect of conjugated linkers on device performance. The new dyes showed strong light-harvesting ability in the visible region with relatively high molar absorption coefficients (>21 800 M cm). This can be attributed to their intrinsic charge transfer (CT) from the arylamine to the acceptor group.

Encapsulation of Biosynthesized Nanosilver in Silica Composites for Sustainable Antimicrobial Functionality.

Silver nanoparticles (AgNPs) have become known as a broad-spectrum antimicrobial agent. The antimicrobial activity of AgNPs is dependent on the particle size and the dispersion status. In this study, a simple and effective approach is developed for sequestering the biosynthesized AgNPs in silica composites during the gel formation of MCM-41.

Erratum: Novel and Stable D-A-π-A Dyes for Efficient Solid-State Dye-Sensitized Solar Cells.

[This corrects the article DOI: 10.1021/acsomega.7b00067.

Erratum: Superior Stability and Efficiency Over 20% Perovskite Solar Cells Achieved by a Novel Molecularly Engineered Rutin-AgNPs/Thiophene Copolymer.

[This corrects the article DOI: 10.1002/advs.201800568.

Superior Stability and Efficiency Over 20% Perovskite Solar Cells Achieved by a Novel Molecularly Engineered Rutin-AgNPs/Thiophene Copolymer.

Perovskite solar cells (PSCs) with efficiencies greater than 20% have been realized mostly with expensive spiro-MeOTAD hole-transporting material. PSCs are demonstrated that achieve stabilized efficiencies exceeding 20% with straightforward low-cost molecularly engineered copolymer poly(1-(4-hexylphenyl)-2,5-di(thiophen-2-yl)-1-pyrrole) (PHPT-py) based on Rutin-silver nanoparticles (AgNPs) as the hole extraction layer. The Rutin-AgNPs additive enables the creation of compact, highly conformal PHPT-py layers that facilitate rapid carrier extraction and collection.

Molecular Engineering of D-D-π-A-Based Organic Sensitizers for Enhanced Dye-Sensitized Solar Cell Performance.

A series of molecularly engineered and novel dyes WS1, WS2, WS3, and WS4, based on the D35 donor, 1-(4-hexylphenyl)-2,5-di(thiophen-2-yl)-1-pyrrole and 4-(4-hexylphenyl)-4-dithieno[3,2-:2',3'-]pyrrole as π-conjugating linkers, were synthesized and compared to the well-known LEG4 dye. The performance of the dyes was investigated in combination with an electrolyte based on Co(II/III) complexes as redox shuttles. The electron recombination between the redox mediators in the electrolyte and the TiO interface decreases upon the introduction of 4-hexylybenzene entities on the 2,5-di(thiophen-2-yl)-1-pyrrole and 4-dithieno[3,2-:2',3'-]pyrrole linker units, probably because of steric hindrance.

Novel and Stable D-A-π-A Dyes for Efficient Solid-State Dye-Sensitized Solar Cells.

Two novel organic donor-acceptor-π-acceptor sensitizers, W7 and W8, have been applied in efficient solid-state dye-sensitized solar cells (ssDSSCs). Using 2,2',7,7'-tetrakis(,-di--methoxyphenyl-amine) 9,9'-spirobifluorene (Spiro-OMeTAD) as hole-transport material (HTM), an excellent power conversion efficiency of 6.9% was recorded for W7, together with an excellent photocurrent of 10.

TiO₂ nanotube-based dye-sensitized solar cell using new photosensitizer with enhanced open-circuit voltage and fill factor.

We report the synthesis and characterization of a high molar extinction coefficient ruthenium complex sensitizer (Ru (6,6'-(COOEt)(2)-2,2'-bpy)(2)(Cl)(2)). In conjugation with TiO(2) nanotube arrays as a photoactive material and iodine/iodate redox electrolyte, we fabricated efficient dye-sensitized solar cell device showing a conversion efficiency of 3.94% measured under the air mass 1.

Designed synthesis of multi-electrochromic systems bearing diaryl ketone and isophthalates.

New multi-electrochromic systems have been developed through the combination of a diaryl ketyl radical system with isophthalate-based electrochromic materials. The location of the isophthalate group in compounds is very critical to obtaining different colors in the multi-electrochromism.

Designed synthesis of ferrocenylanthraquinones and their bifunctional electrochromic properties.

New bifunctional electrochromic systems were developed by combination of reductive anthraquinone with oxidative ferrocene redox systems. The resultant ferrocenylanthraquinones demonstrated enhanced stability in electrochromic performance through the concomitant reductive electrochromism and oxidative counting action. The displayed colors were dependent on the position of the ferrocenyl group.

Molecular design and preparation of bis-isophthalate electrochromic systems having controllable color and bistability.

New electrochromic systems based on bis-isophthalates were designed and prepared. They showed electrochromism behavior by two-electron reduction. The displayed colors showed greatly enhanced bistability and were dependent on the length of the conjugated bridge between the two isophthalate groups.