Constructing Photocatalytic Covalent Organic Frameworks with Aliphatic Linkers.

Photocatalytic covalent organic frameworks (COFs) are typically constructed with rigid aromatic linkers for crystallinity and extended π-conjugation. However, the essential hydrophobicity of the aromatic backbone can limit their performances in water-based photocatalytic reactions. Here, we for the first time report the synthesis of hydrophilic COFs with aliphatic linkers [tartaric acid dihydrazide (TAH) and butanedioic acid dihydrazide] that can function as efficient photocatalysts for HO and H evolution.

Research on autonomous navigation system of greenhouse electric crawler tractor based on LiDAR.

The application of autonomous navigation technology of electric crawler tractors is an important link in the development of intelligent greenhouses. Aiming at the characteristics of enclosed and narrow space and uneven ground potholes in greenhouse planting, to improve the intelligence level of greenhouse electric crawler tractors, this paper develops a navigation system of electric crawler tractors for the greenhouse planting environment based on LiDAR technology. The navigation hardware system consists of five modules: the information perception module, the control module, the communication module, the motion module, and the power module.

Light-regulating chirality of metallacages featuring dithienylethene switches.

Dynamic chiral superstructures are of vital importance for understanding the organization and function of chirality in biological systems. However, achieving high conversion efficiency for photoswitches in nanoconfined architectures remains challenging but fascinating. Herein, we report a series of dynamic chiral photoswitches based on supramolecular metallacages through the coordination-driven self-assembly of dithienylethene (DTE) units and octahedral zinc ions, thereby successfully achieving an ultrahigh photoconversion yield of 91.