The rapid growth in dataset sizes in modern deep learning has significantly increased data storage costs. Furthermore, the training and time costs for deep neural networks are generally proportional to the dataset size. Therefore, reducing the dataset size while maintaining model performance is an urgent research problem that needs to be addressed.
View Article and Find Full Text PDFIn the face of increasingly growing health demands and the impact of various public health emergencies, it is of great significance to study the regional differences in the allocation efficiency of the rural public health resources and its improvement mechanism. In this paper, the game competition relationship is included in the evaluation model, and the game cross-efficiency model is used to measure the allocation efficiency of the rural public health resources in 31 provinces of China from 2008 to 2017. Then, the Theil index model and the Gini index model are applied in exploring the regional differences in the allocation efficiency of rural public health resources and its sources.
View Article and Find Full Text PDFPhosphorus-rich metal phosphides have very high lithium storage capacities, but they are difficult to prepare. A low-temperature phosphorization method based on Mg reducing PCl in ZnCl molten salt at 300 °C is developed to synthesize phosphorus-rich CuP @C from a Cu-MOF derived Cu@C composite. Abnormal oxidation of Cu by Zn in the molten salt is observed, which leads to the porous honeycomb nanostructure and homogeneously distributed ultrafine CuP nanocrystals.
View Article and Find Full Text PDFInt J Environ Res Public Health
October 2019
The development of the agricultural economy has brought the agricultural pollution, and agricultural pollution has restrained the growth of the agricultural economy and endangered public health. Since the Economic Reform opened up, China has promulgated many policies that have benefited farmers, developed the agricultural economy, and improved agricultural material levels. However, the growth in the agricultural economy has also resulted in significant environmental pollution from pesticides, agricultural fertilizers and agricultural plastic film.
View Article and Find Full Text PDFA novel mixed-mode coating-based solid-phase microextraction (SPME) fiber was prepared by chemical bonding dimethyloctadecyl [3-(trimethoxysilyl) propyl] ammonium chloride and 3-(trimethoxysilyl)-1-propanamine, the sol-gel precursors, on an anodized Ti wire, aiming to effectively adsorb perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA). The anodized Ti wire with uniform TiO2 nanotube arrays provides high mechanical strength and strong adhesion to the mixed-mode coating. The prepared fiber shows excellent organic solvent stability due to the covalent bonding between the coating and the fiber, and significantly higher extraction efficiency than the commercial fibers, 100 μm polydimethylsiloxane and 85 μm polyacrylate fiber, due to the synergistic extraction effects of the coating functional groups.
View Article and Find Full Text PDFA novel solid-phase microextraction (SPME) fiber was prepared by polymerization of an organic-inorganic hybrid polymeric coating on an anodized and derived Ti wire, and applied for the analysis of polycyclic aromatic hydrocarbons from environmental samples followed by high performance liquid chromatography (HPLC) analysis. A polyhedral oligomeric silsesquioxane (POSS) reagent containing methacryl substituent groups was used as an organic-inorganic hybrid cross-linker, and copolymerized with methyl methacrylate (MMA) to fabricate the hybrid coating via thermally initiated free radical polymerization in a glass capillary mold. The prepared fiber can be easily withdrawn from the glass capillary mold by controlling the polymerization conditions, especially polymerization solvent.
View Article and Find Full Text PDFThis study reported for the first time the use of cholesterol-functionalized magnetic nanoparticles (Fe3O4@SiO2@Chol) for the determination of polycyclic aromatic hydrocarbons (PAHs) in traditional Chinese medicine samples (TCMs) by high performance liquid chromatography (HPLC) coupled with fluorescence detection. The method was efficient, environmentally friendly, and fast. The solvent consumption of the proposed column is only half of the conventional column but with higher efficiency.
View Article and Find Full Text PDFMetal-organic frameworks, a new class of materials with high surface area and great porosity, have been widely applied in gas sorption. It is generally known that metal-organic framework 5 cannot be applied in aqueous phase since it is water sensitive. However, this work reveals that the derived material of metal-organic framework 5 is a good SPE sorbent that can be applied to aqueous phases.
View Article and Find Full Text PDFAn octadecyl-functionalized solid-phase microextraction (SPME) fiber was prepared by sol-gel technology with an anodized Ti wire as the substrate and dimethyloctadecyl[3-(trimethoxysilyl)propyl]ammonium chloride (C(18)-TMS) and tetraethoxysilane (TEOS) as sol-gel precursors. The anodized Ti wire has high mechanical strength and has numerous titanol groups on its surface for sol-gel reactions, consequently offering better performances than the commercial fragile fused silica substrate. The C(18)-TMS/TEOS sol-gel coated fiber has good thermal stability and stability against organic solvents.
View Article and Find Full Text PDFBackground: Tricuspid regurgitation (TR) is common in patients with mitral valve disease; however, there are no straightforward, rapidly determinably criteria available for deciding whether TR repair should be performed during mitral valve replacement. The aim of our retrospective study was to identify a simple and fast criterion for determining whether TR repair should be performed in patients undergoing mitral valve replacement.
Methods: We reviewed the records of patients who underwent mitral valve replacement with or without (control) TR repair (DeVega or Kay procedure) from January 2005 to December 2008.