Transportation process of nano scale zero valent iron (nZVI) in clay-rich soils is complicated and crucial for in-situ remediation of contaminated sites. A coupled computational fluid dynamic and discrete element method (CFD-DEM) was used to investigate the interplays of repulsive and attractive forces and the injection velocity of this process. The screened Coulomb's law was used to represent the electrostatic interaction, and surface energy density was introduced to represent the effects of the van der Waals interaction.
View Article and Find Full Text PDFThe pick-up, migration, deposition, and clogging behaviors of fine particles are ubiquitous in many engineering applications, including contaminant remediation. Deposition and clogging are detrimental to the efficiency of environmental remediation, and their mechanisms are yet to be elucidated. Two-dimensional microfluidic models were developed to simulate the pore structure of porous media with unified particle sizes in this study.
View Article and Find Full Text PDFOwing to its high surface area and high surface charge density, clay, either contaminated with heavy metal ions or modified with organic additives as barrier materials, is difficult to assess and monitor. Complex dielectric permittivity (κ*) showed promising potential in tackling the above issues. In this study, the complex dielectric permittivity (κ*) of clays modified with a surfactant, four polymers, and four metal ions was measured at frequencies from 0.
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