Environmental remediation and sustainable design of iron oxide nanoparticles for removal of petroleum-derived pollutants from water: A critical review.

The global problem of major oil spills not only generates crude oil pollution, but produces many derivatives that pose ecological and human health challenges. While extensive research has focused on understanding the types of these contaminants, their transport modes, detection techniques, and ecotoxicological impacts, there are still significant research gaps in mechanisms for removal of petroleum-derived pollutants by iron oxide nanoparticles (IONPs). This work summarizes systematically the types and green synthesis of IONPs for the environmental remediation of various petroleum contaminants.

Nanocolloids in the soil environment: Transformation, transport and ecological effects.

Nanocolloids (Ncs) are ubiquitous in natural systems and play a critical role in the biogeochemical cycling of trace metals and the mobility of organic pollutants. However, the environmental behavior and ecological effects of Ncs in the soil remain largely unknown. The accumulation of Ncs may have detrimental or beneficial effects on different compartments of the soil environment.

Oxygen-bridging Fe, Co dual-metal dimers boost reversible oxygen electrocatalysis for rechargeable Zn-air batteries.

Rechargeable zinc-air batteries (ZABs) are regarded as a remarkably promising alternative to current lithium-ion batteries, addressing the requirements for large-scale high-energy storage. Nevertheless, the sluggish kinetics involving oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) hamper the widespread application of ZABs, necessitating the development of high-efficiency and durable bifunctional electrocatalysts. Here, we report oxygen atom-bridged Fe, Co dual-metal dimers (FeOCo-SAD), in which the active site Fe-O-Co-N moiety boosts exceptional reversible activity toward ORR and OER in alkaline electrolytes.

Environmental applications and risks of engineered nanomaterials in removing petroleum oil in soil.

Oil-contaminated soil posed serious threats to the ecosystems and human health. The unique and tunable properties of engineered nanomaterials (ENMs) enable new technologies for removing and repairing oil-contaminated soil. However, few studies systematically examined the linkage between the change of physicochemical properties and the removal efficiency and environmental functions (e.

[Research Progress in Reducing Pollution and Sequestration of Carbon by Carbon Neutral Plants].

Under the dual constraints of economic development and ecological carrying capacity, it is necessary to explore more technical means to achieve carbon neutrality and peak in China. Plants are important carriers of terrestrial and marine carbon sink systems, whereas phytoremediation is also a scientific method to remedy environmental pollution. However, the current studies mostly focus on the single aspect of plant carbon sequestration (including both the reduction of pollutant concentrations in environmental media and degradation of pollutants) or plant pollution reduction, without considering the dual benefits of plant pollution reduction and carbon sequestration.

Algal extracellular polymeric substance compositions drive the binding characteristics, affinity, and phytotoxicity of graphene oxide in water.

Graphene oxide (GO, a popular 2D nanomaterial) poses great potential in water treatment arousing considerable attention regarding its fate and risk in aquatic environments. Extracellular polymeric substances (EPS) exist widely in water and play critical roles in biogeochemical processes. However, the influences of complex EPS fractions on the fate and risk of GO remain unknown in water.

Magnetic iron-based nanoparticles biogeochemical behavior in soil-plant system: A critical review.

Increasing attention is being given to magnetic iron-based nanoparticles (MINPs) because of their potential environmental benefits. Owing to the earth abundance and high utilization of MINPs, as well as the significant functions of Fe in sustainable agriculture and environmental remediation, an understanding of the environmental fate of MINPs is indispensable. However, there are still knowledge gaps regarding the largely unknown environmental behaviors and fate of MINPs in soil-plant system.

Iron oxide nanoparticles in the soil environment: Adsorption, transformation, and environmental risk.

Iron oxide nanoparticles (IONPs) have great application potential due to their multifunctional excellence properties, leading to the possibility of their release into soil environments. IONPs exhibit different adsorption properties toward environmental pollutants (e.g.

Diatomic catalysts for Fenton and Fenton-like reactions: a promising platform for designing/regulating reaction pathways.

The optimization of the single-atom catalyst (SAC) performance has been the hot spot for years. It is widely acknowledged that the incorporation of adjacent single-atom sites (diatomic catalysts (DACs)) can enable synergistic effects, which can be used in cascade catalysis, dual-function catalysis, and performance regulation of intrinsic active sites. DACs have been widely applied in the CO reduction reaction (CORR), oxygen reduction reaction (ORR), hydrogen evolution reaction (HER), ; however, their application is limited in Fenton or Fenton-like reactions.

Microplastics Weaken the Adaptability of Cyanobacterium sp. to Ocean Warming.

Ocean warming (OW) caused by anthropogenic activities threatens ocean ecosystems. Moreover, microplastic (MP) pollution in the global ocean is also increasing. However, the combined effects of OW and MPs on marine phytoplankton are unclear.

The optimized Fenton-like activity of Fe single-atom sites by Fe atomic clusters-mediated electronic configuration modulation.

The performance optimization of isolated atomically dispersed metal active sites is critical but challenging. Here, TiO@Fe species-N-C catalysts with Fe atomic clusters (ACs) and satellite Fe-N active sites were fabricated to initiate peroxymonosulfate (PMS) oxidation reaction. The AC-induced charge redistribution of single atoms (SAs) was verified, thus strengthening the interaction between SAs and PMS.

Effect of natural soil nanocolloids on the fate and toxicity of cadmium to rice (Oryza sativa L.) roots.

Toxic heavy metals are common contaminants and will most likely interact with ubiquitous natural nanocolloids (Ncs) in the soil environment. However, the effect of soil Ncs on the fate and health risk of cadmium (Cd) have not been well addressed. Here, the interaction between Ncs and Cd is investigated using two-dimensional correlation spectroscopy (2DCOS) combined with synchronous fluorescence and Fourier transform infrared spectroscopy.

Natural nanocolloids regulate the fate and phytotoxicity of hematite particles in water.

Hematite (the most abundant iron oxide polymorph) is widely detected in the water environment and has attracted considerable attention. Natural nanocolloids (Ncs) exist ubiquitously in surface waters and play critical roles in biogeochemical processes. However, the influences of Ncs on the fate and phytotoxicity of hematite remain unknown.

Enhanced carbon emission driven by the interaction between functional microbial community and hydrocarbons: An enlightenment for carbon cycle.

Soil microbial communities are usually regarded as one of the key players in the global element cycling. Moreover, an important consequence of oil contamination altering the structure of microbial communities is likely to result in an increased carbon emission. However, understanding of the complex interactions between environmental factors and biological communities is clearly lagging behind.

Triclosan Reprograms Immunometabolism and Activates the Inflammasome in Human Macrophages.

To gather enough energy to respond to harmful stimuli, most immune cells quickly shift their metabolic profile. This process of immunometabolism plays a critical role in the regulation of immune cell function. Triclosan, a synthetic antibacterial component present in a wide range of consumer items, has been shown to cause immunotoxicity in a number of organisms.

Integrating FTIR 2D correlation analyses, regular and omics analyses studies on the interaction and algal toxicity mechanisms between graphene oxide and cadmium.

Graphene oxide (GO, a popular 2D graphene-based nanomaterial) has developed quickly and has received considerable attention for its applications in environmental protection and pollutant removal. However, significant knowledge gaps still exist about the interaction characteristic and joint toxicity mechanism of GO and cadmium (Cd) on aquatic organisms. In this study, GO showed a high adsorption capacity (120.

Pulmonary Fibrosis Induced by CdSe Nanorods and the Therapy with Modified Procyanidinere.

The CdSe nanorod as a one-dimensional nanostructure has an excellent performance in many fields, such as healthcare, new energy, and environmental protection. Thus, it is crucial to investigate its potential adverse health effects prior to their wide exposure. The lung tissue would be the main target organ after CdSe nanorods enter living systems.

Anthropogenic impacts on the biodiversity and anti-interference ability of microbial communities in lakes.

Lakes are critical for biogeochemical and ecological processes and are sensitive and vulnerable to anthropogenic disturbances, but how and to what extent human activities disturb the biodiversity in lakes remain unknown. Here, we showed the microbial diversity in 46 lakes and assessed the influence of 27 anthropogenic factors. We found that the economic level (e.

Direct and Indirect Genotoxicity of Graphene Family Nanomaterials on DNA-A Review.

Graphene family nanomaterials (GFNs), including graphene, graphene oxide (GO), reduced graphene oxide (rGO), and graphene quantum dots (GQDs), have manifold potential applications, leading to the possibility of their release into environments and the exposure to humans and other organisms. However, the genotoxicity of GFNs on DNA remains largely unknown. In this review, we highlight the interactions between DNA and GFNs and summarize the mechanisms of genotoxicity induced by GFNs.

Nanocolloids, but Not Humic Acids, Augment the Phytotoxicity of Single-Layer Molybdenum Disulfide Nanosheets.

Engineered nanomaterials (ENMs), especially transition metal dichalcogenide (TMDC), have received great attention in recent years due to their advantageous properties and applications in various fields and are inevitably released into the environment during their life cycle. However, the effect of natural nanocolloids, widely distributed in the aquatic environment, on the environmental transformation and ecotoxicity of ENMs remains largely unknown. In this study, the effects of natural nanocolloids were compared to humic acid on the environmental transformation and ecotoxicity of single-layer molybdenum disulfide (SLMoS), a representative TMDC.

Graphene oxide nanosheets mitigate the developmental toxicity of TDCIPP in zebrafish via activating the mitochondrial respiratory chain and energy metabolism.

Graphene oxide (GO), a novel two-dimension carbon nanomaterial, has showed tremendous potential for utilization in intelligent manufacturing and environmental protection. In parallel, tris(1,3-dichloro-2-propyl) phosphate (TDCIPP) is widely distributed in the water environment and represents a great threat to ecosystem health. However, the related knowledge remained absent regarding the impact of GO on the biological risks of TDCIPP.

Natural Nanocolloids Mediate the Phytotoxicity of Graphene Oxide.

Nanocolloids (Ncs) are ubiquitous in natural surface waters. However, the effects of Ncs on the fate and ecotoxicity of graphene oxide (GO, a popular engineered nanomaterial (ENM)) remain largely unknown. Ncs exhibit strong adsorption affinity ( = 1.

Widely distributed nanocolloids in water regulate the fate and risk of graphene oxide.

The environmental behaviors and risks associated with graphene oxide (GO, a popular 2D nanomaterial) have attracted considerable attention. GO released to aquatic systems will most likely interact with ubiquitous nanocolloids (Nc) in surface water. However, the effects of Nc on the fate and risk of GO remain largely unknown in water.

Integrating Biolayer Interferometry, Atomic Force Microscopy, and Density Functional Theory Calculation Studies on the Affinity between Humic Acid Fractions and Graphene Oxide.

The interactions between nanoparticles and humic acid (HA) are critical to understanding the environmental risks and applications of nanoparticles. However, the interactions between HA fractions and graphene oxide (GO, a popular carbon nanosheet) at the molecular level remain largely unclear. Four HA fractions with molecular weights ranging from 4.

Nanocolloids in Natural Water: Isolation, Characterization, and Toxicity.

Nanocolloids are widespread in natural water systems, but their characterization and ecological risks are largely unknown. Herein, tangential flow ultrafiltration (TFU) was used to separate and concentrate nanocolloids from surface waters. Unexpectedly, nanocolloids were present in high concentrations ranging from 3.