Publications by authors named "Shantanu K Behera"

This work integrates a unique porous carbon with a binary heterostructured NiFeO/CuWO composite to enhance electrocatalytic activity towards the oxygen evolution reaction. The NiFeO/CuWO binary heterostructure was prepared through the conventional co-precipitation method. The porous carbon with turbostratic order was obtained by the selective etching of SiO nanodomains from preceramic polymer-derived SiOC.

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In this work, Ag nanoparticles decorated with NiFeO/CuWO heterostructure were synthesized using the step-wise precipitation method. The influence of varying Ag loading on the NiFeO/CuWO heterostructure and its electrochemical OER performance was extensively studied in 1 M KOH electrolyte. The obtained LSV profile was analyzed to determine the overpotential, Tafel slope, and onset potential.

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A novel two step synthesis from commercial nanocarbon and a preceramic polymer afforded a nanoporous carbon hybrid with specific surface area of 1798 m2 g-1, and porosity in the range of 1-4 nm. Preliminary studies on the supercapacitive behaviour of the material through cyclic voltammetry resulted in an excellent specific capacitance of 333 F g-1.

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This research focuses on the effect of the Y : B ratio on phase purity and the development of thermally stable 10 mol% Eu(3+)-doped YBO3 red phosphor nanomaterial using a novel sodium borohydride based solution precursor route. An equimolar concentration of Y and B leads to the development of chemically and thermally stable un-doped and Eu(3+)-doped YBO3 up to 1300 °C. An impurity phase, Y3BO6, was observed at a higher temperature of around 1400 °C.

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A novel hybrid material for Li ion battery anodes, synthesized from polysiloxane-derived SiCO and nanoparticulate TiO2, exhibited specific capacity in excess of 850 mA h g(-1), fully recoverable capacity after cycling at severe current densities, as high as 20,000 mA g(-1) or 300 C rate, and exceptional stability beyond 1000 charge discharge cycles without capacity fading. Microscopy of the anodes after 3000 cycles showed no degradation or loss of materials.

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Monodispersed Fe(3)O(4) nanoparticles of size ∼10 nm were processed by a simple ultrasonic assisted co-precipitation method, mechanically mixed with graphene oxide, and thermally reduced to form a magnetite-graphene composite. Electrochemical characterization of the Fe(3)O(4)-graphene nanocomposites showed excellent capacity in excess of 1200 mA h g(-1), and exceptional stability during high current cycling for at least 1000 cycles.

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