Elucidation of the Effect of Solar Light on the Near-Infrared Excitation Raman Spectroscopy-Based Analysis of Fabric Dyes.

Colored textiles are valuable physical evidence often found at crime scenes. Analysis of the chemical structure of textiles could be used to establish a connection between fabric found at a crime scene and suspect cloths. High-performance liquid chromatography (HPLC) and mass spectroscopy coupled HPLC are traditionally used for the identification of dyes in fabric.

Near-infrared excitation Raman analysis of Underlying colorants on redyed fabric.

Forensic analysis of fabric is often critically important to establish a relationship between a suspect and a crime scene or demonstrate the absence of such connections. Most of commercially available fabric is colored with primarily organic colorants. These dye substances are highly fluorescent, which limits the use to conventional Raman spectroscopy for the analysis of the colorant content of fabric.