Distribution characteristics and migration trends of hexabromocyclododecanes between seawater-sediment system in different seasons of fishing grounds along the Yellow sea and East China sea coasts.

Pollutants in the ecological environment of fishery seawater are harmful to the survival and reproduction of aquatic organisms. Hexabromocyclododecanes (HBCDs) were 42.9% detected within ND-48.

Occurrence of polyhalogenated carbazoles and the combined effects with heavy metals on variation in bacterial communities in estuarine sediments.

Carbazole (CZ) and eight polyhalogenated carbazoles (PHCZs) were quantified by GC-MS in sediments of 12 estuaries, the interface linking large industrial and living areas to the Bohai Sea, China. These pollutants, heavy metals, and environmental factors caused integrated exposure to sediment bacteria. Four PHCZ congeners were detectable, with ΣPHCZs ranging from 0.

Thin-layer chromatography coupled with HPLC-DAD/UHPLC-HRMS for target and non-target determination of emerging halogenated organic contaminants in animal-derived foods.

In this study, a simple, solvent-saving, and sensitive method was established using high-performance liquid chromatography coupled with high-resolution mass spectrometry to quantitively determine 16 emerging halogenated organic contaminants (HOCs), including polyhalogenated carbazoles, halogenated phenols, and tetrabromobisphenol-A analogs, and to qualitatively identify non-target HOCs in animal-derived food samples. The sample extracts were physically frozen to remove most lipids and further purified by thin-layer chromatography according to the targets polarity. The method detection limit and method quantification limit of 16 HOCs were in the range of 0.

Study of the scavenger and vector roles of microplastics for polyhalocarbazoles under simulated gastric fluid conditions.

Microplastics entering the digestive system of living organisms can serve as a carrier of hydrophobic organic pollutants (HOPs), increasing their exposure levels and the health risks they pose to both humans and animals. The desorption kinetics of six polyhalocarbazoles (PHCZs) from 5 mm and 0.15 mm polypropylene (PP) and polyvinyl chloride (PVC) microplastic particles were assessed using a combined microplastics and food system, representing the gastric system of vertebrates and invertebrates.