Detection of nickel by chemo and fluoro sensing technologies.

Sensing technology for heavy metal detection is very crucial for recent decades as the detection method is very easy, rapid, and does not require any pre-treatment of the sample. Nickel is a trace element in the human body and basically a moderate toxic element. There is a limited number of chemo and fluoro sensors reported for nickel as compared to other transition metal ion.

Sensing study of quinoxaline analogues with theoretical calculation, single-crystal X-ray structure and real application in commercial fruit juices.

Single-crystal X-ray structures of dimeric quinoxaline aldehyde (QA), quinoxaline dihydrazone (DHQ) and HQNM (Goswami S 2013 , 5075-5077. (doi:10.1016/j.

A new pyrene based highly sensitive fluorescence probe for copper(II) and fluoride with living cell application.

A new pyrene based fluorescence probe has been synthesized for fluorogenic detection of Cu(2+) in acetonitrile-aqueous media (7 : 3 CH3CN-HEPES buffer, v/v, at pH 7.5) with bioimaging in both prokaryotic (Candida albicans cells) and eukaryotic (Tecoma stans pollen cells) living cells. The anion recognition properties of the sensor have also been studied in acetonitrile by fluorescence methods which show remarkable sensitivity toward fluoride over other anions examined.

Dual channel selective fluorescence detection of Al(III) and PPi in aqueous media with an 'off-on-off' switch which mimics molecular logic gates (INHIBIT and EXOR gates).

In this study, we have synthesized a simple Schiff base type isophthaloyl salicylaldehyde hydrazone (ISH) moiety which selectively detects Al(III) and PPi with a fluorescence enhancement at two different wavelengths in aqueous solution. The sensing phenomenon is also reversible and thus the sensor beautifully mimics logic gates (INHIBIT and EXOR gates).

Computational study of urea and its homologue glycinamide: conformations, rotational barriers, and relative interactions with sodium chloride.

Conformational behaviors of urea and glycinamide have been investigated using the B3LYP functional with the 6-311+G* and 6-311+G** basis sets. Urea monomers have nonplanar minima at all the levels studied, even in the aqueous phase. In the case of glycinamide, the intramolecular hydrogen bond formed from the amide to the amine is important for stabilizing the global minimum.