Influence of Ag Nanostructure Location on the Absorption Enhancement in Polymer Solar Cells.

The optical absorption enhancement in Ag nanocube (NC)- and nanosphere (NS)-embedded poly[ N-9'-heptadecanyl-2,7-carbazole- alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)]:[6,6]-phenyl C-butyric acid methyl ester active layer was calculated using three-dimensional finite-difference time domain simulations. The simulations were carried out by incorporating Ag nanostructures as a two-dimensional array at various locations in the active layer matrix. High absorption enhancements of 53 and 61% were achieved with NSs and NCs, respectively, when they were incorporated at the top portion of the active layer.