Efficient photocatalytic degradation of metronidazole in wastewater under simulated sunlight using surfactant- and CuS-activated zeolite nanoparticles.

Hexadecyltrimethylammonium-bromide-activated zeolite nanoparticles coated with copper sulfide (ZEO/HDTMA-Br/CuS) was evaluated as a photocatalyst under sunlight for the degradation of metronidazole (MET). The surface and structural characteristics of ZEO/HDTMA-Br/CuS and other materials used in this study were analyzed using field emission-scanning electron microscopy, Fourier transform infrared and ultraviolet-visible diffuse reflectance spectroscopies, X-ray diffraction, Brunauer-Emmett-Teller surface area and Barrett-Joyner-Halenda pore size and volume analyses, and pH of zero charge test. ZEO/HDTMA-Br/CuS exhibited excellent surface and structural catalytic properties.