Duplex stainless steels, known for their excellent corrosion resistance, are employed in a variety of chloride solutions-acidic, neutral, and alkaline-due to a stable passive film that forms on their surfaces. This study involved polarization tests, EIS (Electrochemical Impedance Spectroscopy) measurements, Mott-Schottky plots, and XPS (X-Ray Photoelectron Spectroscopy) analyses in both static and dynamic conditions across acidic (1NaCl + 0.1N HCl, pH 1.
View Article and Find Full Text PDFWe fabricated MAPbI perovskite thin films with ZnO on a glass substrate, in which a passivation layer (Phenethylammonium iodide (PEAI); p-methoxyphenethylammonium iodide (CHO-PEAI); 2-methoxyethylammonium iodide (MEAI)) was inserted between two layers. In order to understand the effect of the insertion of each passivation material on the transfer efficiency of the photo-generated electrons from MAPbI to ZnO, we observed the near-field heterodyne transient grating (NF-HD-TG) responses of each film and investigated the component arising from the recombination of the trapped electrons at the ZnO surface. Based on the accelerated recombination between photo-generated holes remaining in the MAPbI layer and surface-trapped electrons in ZnO and the increase in the number of the trapped electrons in ZnO when either CHO-PEAI or PEAI was applied, we successfully revealed that the charge transfer efficiency was enhanced by the insertion of the passivation materials including a benzene ring stabilizing the defect states.
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January 2023
Dry canisters used in nuclear power plants can be subject to localized corrosion, including stress corrosion cracking. External and residual tensile stress can facilitate the occurrence of stress corrosion cracking. Residual stress can arise from welding and plastic deformation.
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