A comparative study of doping aliovalent ions, Zr- or Al-, into Ni-rich Li(Ni,Co,Mn)O cathode materials is conducted in terms of the electrochemical properties and chemical analysis, especially on the surface region. The solubility and chemical composition for the given sol-gel treatment matches well with the computational results with which the infinitesimal Zr-coating is identified as exhibiting increased charge capacity with prolonged cycle life. Specifically, the whole process can be understood by the suppressed lithium-ion charge transfer resistance () during the cycles, which can be facilitated by the decreased NiO formation during the cyclic reactions.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2021
Many research groups have been interested in the quartz crystal microbalance (QCM)-based gas sensors due to their superb sensitivity originated from direct mass sensing at the ng level. Despite such high sensitivities observed from QCM sensors, their ability to identify gas compounds still needs to be enhanced. Herein, we report a highly facile method that utilizes microcolumns integrated on a QCM gas-responsive system with enhanced chemical selectivity for sensing and ability to identify volatile organic compound single gases.
View Article and Find Full Text PDFUnlabelled: We herein report an investigation of the device performance capabilities and impedance characteristics of solution-processed organic light-emitting devices (OLEDs) with all-water-processable triple-stacked hole-selective layers (HSLs) on an indium-tin-oxide (ITO) anode, fabricated using a simple coating technique. Highly smooth and homogeneous triple-stacked layers were deposited via horizontal-dip- (H-dip-) coating using aqueous dispersions of graphene oxide (GO), molybdenum oxide (MoO), and poly(ethylenedioxy thiophene):poly(styrene sulfonate) (
Pedot: PSS). From the triple-stacked GO/MoO/
Pedot: PSS HSLs used as hole-injection layers (HILs) in the OLEDs, which outperform a conventional single HIL of
Pedot: PSS, it was found that OLEDs with triple-stacked HILs exhibited characteristic impedance properties, including low parallel resistance with trap-free space-charge-limited conductivity.