Heterolytic Scission of Hydrogen Within a Crystalline Frustrated Lewis Pair.

We report the heterolysis of molecular hydrogen under ambient conditions by the crystalline frustrated Lewis pair (FLP) 1-{2-[bis(pentafluorophenyl)boryl]phenyl}-2,2,6,6-tetramethylpiperidine (KCAT). The gas-solid reaction provides an approach to prepare the solvent-free, polycrystalline ion pair KCATH2 through a single crystal to single crystal transformation. The crystal lattice of KCATH2 increases in size relative to the parent KCAT by approximately 2%.

New type of Li ion conductor with 3D interconnected nanopores via polymerization of a liquid organic electrolyte-filled lyotropic liquid-crystal assembly.

A new type of polymer electrolyte material for Li ion transport has been developed. This material is based on a polymerizable lyotropic (i.e.

Health content can advance the clinical care process.

Many health Web planners use health content as a way to encourage people to visit their site. Their goals often include offering the information as a service to the community, marketing their health services, or, for commerical sites, selling ads, But for a few organizations, the health content is an integral part of their care process.