J Environ Sci Health A Tox Hazard Subst Environ Eng
July 2006
Article Synopsis
The study investigated how to reduce hexavalent chromium (Cr(VI)) to trivalent chromium (Cr(III)) using a tubular reactor in both continuous and batch modes.
It was found that the reduction process involves not just the oxidation of iron from sacrificial steel anodes, but also a secondary reaction where Fe(III) is reduced back to Fe(II), suggesting a catalytic effect.
The research highlighted the importance of pH levels (1 to 2) on the solubility of the generated species, with significant reductions in chromium concentrations observed, dropping from 1000 mg/L to as low as 0.5 mg/L after treatment times between 25 to 320 minutes.