Coordination Polymer Based on a Triangular Carboxylate Core {Fe(μ-O)(μ-OCR)} and an Aliphatic Diamine.

Interaction of the pre-organized complex of iron(II) trimethylacetate and 1,10-phenanthroline (phen) [Fe(piv)(phen)] () (piv = (Me)CCO)) with 1,6-diaminohexane (dahx) in anhydrous acetonitrile yielded a 1D coordination polymer [FeO(piv)(dahx)] () and an organic salt of pivalic acid (Hdahx)(piv) (). The structure of the obtained compounds was determined by single-crystal X-ray diffraction analysis. The phase purity of the complexes was determined by powder X-ray diffraction analysis.