The Brønsted-Evans-Polanyi relationship in oxygen exchange of fuel cell cathode material SrCoTaO with the gas phase.

Perovskite related oxides ABO3-δ exhibiting mixed ionic-electronic conductivity (MIEC) possess large deviations from the oxygen stoichiometry. When providing excellent application potential, this feature also makes it very difficult to study the reaction mechanism between such oxides and molecular oxygen, also known as the oxygen reduction reaction. The complexity of the theoretical interpretation of kinetic experiments originates from the significant dependence of the kinetic and equilibrium properties of MIEC oxides on δ.

Oxygen release technique as a method for the determination of "δ-pO2-T" diagrams for MIEC oxides.

A new approach to the determination of oxygen nonstoichiometry (δ) of MIEC oxides as a continuous function of pO2 at high temperatures was developed. The description of the model allowing one to distinguish the contribution of oxygen released from the samples to the partial pressure of oxygen at the outlet of the continuous-flow fixed-bed reactor after the stepwise change of the oxygen partial pressure of inlet gas from 0.2 to 10(-5) atm and to calculate the dependence of δ on pO2 is presented.