Nonlinear charge regulation for the deposition of silica nanoparticles on polystyrene spherical surfaces.

Hypothesis: We describe the deposition behavior of monodispersed silica nanoparticles on polystyrene spherical particles by using modified pairwise DLVO (Derjaguin-Landau-Verwey-Overbeek) interaction force profiles at pH values between two and twelve. Our modified model contains a new nonlinear charge regulation parameter that considers redistribution of ions, which allows us to realistically express the electrical double layer (EDL) interaction forces.

Experiments: Silanol-terminated silica nanoparticles (7.

Correlation between the Compressive Strength and Ultrasonic Pulse Velocity of Cement Mortars Blended with Silica Fume: An Analysis of Microstructure and Hydration Kinetics.

The effect of the replacement rate of silica fume (SF) on the correlation between the compressive strength and ultrasonic pulse velocity (UPV) of cement mortar was experimentally analyzed. Specimens were fabricated with different replacement rates of SF, the compressive strength and UPV were measured, and isothermal calorimetry and mercury intrusion porosimetry tests were conducted to analyze the effects of replacement on the hydration kinetics and microstructures on these properties. Field emission scanning electron microscopy analysis was performed to observe SF particles and microstructure.

Cross-Linker-Controlled Ostwald Ripening in Emulsion Polymerization of Hollow Copolymer Nanoparticles.

We propose a synthesis method for hollow copolymer nanoparticles, in which the size is controllable by the wettability of the materials designed by relative energy difference (RED). We investigated the influence of cross-linkers in RED and the hollow polymer nanoparticle synthesis. The size of the nanoparticles was characterized by scanning electron microscopy and transmission electron microscopy images.

Autogenous Healing of Early-Age Cracks in Cementitious Materials by Superabsorbent Polymers.

The effect of superabsorbent polymers (SAPs) on autogenous crack healing in cementitious materials with early-age cracking was investigated. SAP-containing samples exposed to wet/dry cycles showed better autogenous healing than those only exposed to wet conditions, as determined by water flow and compressive strength recovery tests. The water flow rates through cracks (380 ± 40 µm) in cement paste and cement mortar containing 1.

Autogenous Healing of Early-Age Cementitious Materials Incorporating Superabsorbent Polymers Exposed to Wet/Dry Cycles.

This study experimentally investigated the autogenous healing performances of cementitious materials incorporating superabsorbent polymers (SAPs) after exposure to eight cycles of wet/dry conditions. In each cycle, cracked cement paste specimens with different SAP dosages were exposed to wet conditions for 1 h, during which capillary water absorption tests were conducted, and then exposed to dry conditions for 47 h. The test results reveal that the initial sorptivity values of the reference, 0.