The catalytic combustion of acetaldehyde was studied using various types of Co oxides and Co-PC. The Co oxides and Co-PC were characterized using an X-ray diffractometer (XRD), X-ray photo-electron spectroscopy (XPS), and a particle sizing analyzer. The Co-PC and CoO were converted into Co₃O₄ under an air atmosphere at 450 °C, and the results were confirmed using the XRD and XPS.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
July 2021
In this study, we investigated the oxidation of acetaldehyde over Co/carbon black catalysts. All experiments were conducted in the temperature range of 200-440 °C, at an acetaldehyde concentration of 0.94 mol% in air, and using Co loading amounts in the range of 2-60 wt%.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
July 2021
In this study, we investigated the characteristics of high-content steel briquettes produced using various nanoscale solid binders and steel byproducts (SS, SCS, SLD, and BSD). The average particle size was 0.171 nm for S5, 0.
View Article and Find Full Text PDFMesoporous gamma alumina (MGA) was synthesized using aluminum trash containers by a low temperature hydrothermal method for effectively removing phosphate from wastewater. The effects of precursor concentrations in gel precipitation process over the pore size and surface area of MGA were investigated in detail. The phosphate removal by prepared MGAs were rigorously investigated through adsorption isotherms and kinetics of phosphate.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
February 2019
Fluoride is important to aquatic environment and health aspects, and the optimal fluoride concentration in water is below 1 mg/L. In this study, the micro-nano bubble pretreatment was applied to remove fluoride ions in the water phase. The pH control by calcium hydroxide (Ca(OH)₂), and coagulation processes with poly aluminum chloride (PAC), aluminum sulfate (Alum), F900 and two kinds of polymer named as A-polymer and A430P polymer were applied for the pretreated wastewater.
View Article and Find Full Text PDFIn this study, the effect on pore volume and compressive strength was investigated using nano-sized blast furnace slag (BFS), fly ash (FA), and desulfurized gypsum (DG). In the chemical compositions of BFS and FA, the sum of the four ingredients, CaO, SiO2, A12O3, and MgO were shown to account for 97% and 87%, respectively. Particles smaller than 50 nm were shown to be distributed in the range of 47.
View Article and Find Full Text PDFTo evaluate the sterilize efficiency of nano-sized recycled aggregates (RAs), several types of RAs were examined for the purpose of environmental stamping out procedure. The poultry (e.g.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
February 2018
In this study, the nano-sized fume biogas production from food waste was investigated using lab scale semi-continuous stirred tank reactor (SCSTR) at 35 °C with 30d HRT and 30L working volume. The mesophilic digestion test was performed with three different feed materials (food waste) and food to microorganism (F/M) ratios (0.13, 0.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
February 2016
Catalytic oxidation of methanol was investigated using Pd, Pt and Ru-based catalysts. Experiment was conducted at reaction temperature of 100-220 degrees C with methanol concentration of 3000 ppm and gas hourly space velocity (GHSV) of 16,000 hr(-1). Catalysts were characterized by using Brunauer-Emmett-Teller (BET) method, X-ray diffraction (XRD), field transmission electron microscopy (FE-TEM) and temperature programmed reduction (TPR).
View Article and Find Full Text PDFIn this research, the recycled aggregates (RAs) from blast furnace were solidified with nano-cerium (Ce), and applied to reduce the ionic species (e.g., magnesium sulfate) in the desulfurization industrial wastewater.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
July 2015
This work investigates the effect of reducing agents and stabilizing agent on the preparation of platinum nanoparticles. We used H2PtCl6 as a precursor and hydrogen and sodium borohydride as reducing agents to prepare colloidal platinum nanoparticles. Polyvinylpyrrolidones (PVPs) is used as a stabilizing agent.
View Article and Find Full Text PDFThis study investigates the nano pore structure of non-sintering cement (NSC) matrix. The result of pore structure properties showed no considerable difference in the total pore volume, but presented a large distinction in distribution of pore diameter by cement mixing ratio. The pore-diameter of NSC paste shows that occupation ratio of pore diameter below 10 nm was larger and was smaller than ordinary Portland cement (OPC) and blast-furnace slag cement (BSC) at pore diameter of over 10 nm.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
March 2013
We investigated the influence of a surfactant and reducing agent on the preparation of palladium nanoparticles, characterizing the prepared palladium nanoparticles by Transmission Electron Microscopy (TEM), and X-ray diffractometer (XRD). Colloidal palladium nanoparticles are prepared using PdCl2 as a precursor and polyvinylpyrrolidone (PVP) as a surfactant. In addition, hydrogen and sodium borohydride are used as reducing agents are used to characterize the prepared palladium nanoparticles.
View Article and Find Full Text PDFThis study was conducted to investigate removal of nitrate by nanoscale zero-valent iron (ZVI) particles in aqueous solution. ZVI particles was produced from wasted acid that is by-products of a pickling line at a steel work. The reaction activity of ZVI particles was evaluated through decomposition experiments of NO3-N aqueous solution.
View Article and Find Full Text PDFThe photo-catalytic decomposition of rhodamine B was examined in aqueous nano TiO2 particles dispersions to assess effects of the microwave radiation assisted photo-catalytic process driven by UV radiation. The results of photo-catalytic degradation of rhodamine B showed that the decomposition rate increased with the microwave intensity, UV intensity, TiO2 particle dosages and the circulating fluid velocity. Addition of oxygen gas in the photo-catalytic degradation of rhodamine B increased the reaction rate.
View Article and Find Full Text PDFTo examine the effect of chemical treatment on the adsorption and catalytic activity of nanostructured platinum based catalyst, the aged commercial Pt/AC catalyst was pretreated with sulfuric acid (H2SO4) and a cleaning agent (Hexane). Several reliable methods such as nitrogen adsorption, X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and inductively coupled plasma (ICP) were employed to characterize the aged Pt/AC catalyst and its chemically pretreated Pt/AC catalysts. The catalytic and adsorption activities of nano-structured heterogeneous Pt/AC catalyst were investigated on the basis of toluene oxidation and adsorption isotherm data.
View Article and Find Full Text PDFIn this study, a microwave/UV/TiO(2)/ozone/H(2)O(2) hybrid process system, in which various techniques that have been used for water treatment are combined, is evaluated to develop an advanced technology to treat non-biodegradable water pollutants efficiently. In particular, the objective of this study is to develop a novel advanced oxidation process that overcomes the limitations of existing single-process water treatment methods by adding microwave irradiation to maximize the formation of active intermediate products, e.g.
View Article and Find Full Text PDFThe influence of physicochemical treatments on the catalytic activity of the spent nano-structured three way catalysts (TWCs) was examined to evaluate the possibility of using spent TWCs for removing VOCs. Thermal gases and acid aqueous solutions were used to regenerate the spent nano-structured TWCs. The characterization of the spent catalyst and its modified forms was carried out by using XRD, TEM, ICP, and N2 adsorption-desorption isotherms.
View Article and Find Full Text PDFJ Colloid Interface Sci
June 2004
Adsorption and conversion of various hydrocarbons on monolithic hydrocarbon adsorbers were studied using a new experimental model, temperature-programmed adsorption (TPA). In this study, methyl alcohol, acetone, acetaldehyde, 2,2,4-trimethylpentane, n-octane, and toluene were chosen as model hydrocarbons for cold start of a vehicle. The effect of the hydrocarbon components and oxygen concentration on the TPA curve was investigated.
View Article and Find Full Text PDF