Cr(VI) immobilization by FeS-coated alumina and silica: Effects of pH and surface coating density.

We investigated the feasibility of using FeS-coated alumina and silica for permeable reactive barrier (PRB) applications. By both coated materials, Cr(VI) was reduced to Cr(III), which was immobilized via surface complexation/precipitation at acidic pH, and bulk precipitation at neutral to basic pH. Both pH and surface coating density (the amount of FeS deposits per unit surface area of a supporting matrix) controlled Cr(VI) reduction capacity and [Cr,Fe](OH) composition.