Publications by authors named "Senthil Kumar P"

This study investigates the removal of ibuprofen and diclofenac from aqueous media via a fully pressurized dissolved air flotation system, enhanced by fenugreek-derived saponin, a plant-based biosurfactant. The use of fenugreek saponin in flotation processes distinguishes this work from previous studies as it offers an ecofriendly and efficient alternative to chemical surfactants. The biosurfactant's surface-active properties were confirmed through FT-IR, UV-vis spectroscopy identified key functional groups and structural characteristics of the saponin, NMR provided molecular insights into its bioactive components, and surface tension analyses demonstrated its ability to reduce interfacial tension, indicating effective surfactant behavior.

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Intraductal papillary neoplasms of the bile duct are rare tumors with fibrovascular stalks arising from the bile duct. It is often difficult to diagnose preoperatively, especially from mucinous cystic neoplasms. The incidence is more common in Asian countries and rare in Western countries.

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Degradation of tartrazine dye (TZD) was performed in this study using sulfate radicals (SO) generated from the activated sodium persulfate (SPS) using FeO@PDA nanoparticles (NPs). The NPs were characterized by Fourier transform infrared (FTIR), vibrating sample magnetometer (VSM), X-ray diffraction (XRD), high-resolution scanning electron microscopy (HR-SEM), X-ray photoelectron spectroscopy (XPS), high resolution transmission electron microscopy (HRTEM), and energy-dispersive X-ray spectroscopy (EDX). The average particle size of the NPs was 17.

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In the current research work, an advanced oxidation process was applied to the degradation of Remazol brilliant blue dye (RBBD) using a sulfate radical. FeO@PDA nanoparticles were synthesized using coprecipitation and self-polymerization techniques. Nanoparticle formation was confirmed by XRD, FTIR, FESEM-EDX, VSM, and XPS analyses.

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Article Synopsis
  • - The study investigated bifunctional electrocatalysts for water splitting, focusing on nonprecious materials to enhance sustainable energy solutions.
  • - Researchers developed rGO/MnO/MoS nanohybrids that improved water splitting efficiency by increasing surface area and electroactive sites.
  • - These nanohybrids showed impressive catalytic performance for both hydrogen and oxygen production with low energy requirements, highlighting their potential for renewable energy applications.
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Carbon monoxide poisoning can occur as part of smoke exposure in the burn population. Here we report the case of a 32-year-old, previously healthy male, with carbon monoxide-related blindness after smoke exposure in an apartment fire. Cerebral hypoperfusion was diagnosed using magnetic resonance imaging of the brain, and the patient was diagnosed with cortical visual impairment.

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As an effort to tackle some of the most pressing ecological issues we are currently experiencing, there has been an increasing interest in employing biomass-derived char products in various disciplines. Thermal combustion of biomass results in biochar production, which is a remarkably rich source of carbon. Not only does the biochar obtained by the thermochemical breakdown of biomass lower the quantity of carbon released into the environment, but it also serves as an eco-friendly substitute for activated carbon (AC) and further carbon-containing products.

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Polyaromatic hydrocarbons (PAHs) are the most persistent compounds that get contaminated in the soil and water. Nearly 16 PAHs was considered to be a very toxic according US protection Agency. Though its concentration level is low in the environments but the effects due to it, is enormous.

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Article Synopsis
  • Measuring the concentration of organochlorine pesticides (OCPs) is crucial because they can harm human health and contaminate the environment and food supply.
  • Researchers developed a fluorescent blue emissive-carbon dot (B-CD) that can effectively detect OCPs in real samples, showing high sensitivity and specific binding to different types of OCPs.
  • The fluorescence method demonstrated low detection limits for various OCPs, making it a promising and efficient tool for monitoring pesticide residues in water and agricultural products.
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Pollution is a global menace that poses harmful effects on all the living ecosystems and to the Earth. As years pass by, the available and the looming rate of pollutants increases at a faster rate. Although many treatments and processing strategies are waged for treating such pollutants, the by-products and the wastes or drain off generated by these treatments further engages in the emission of hazardous waste.

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Sodium carboxymethyl cellulose polymer was used as a support matrix in immobilizing activated hydrochar derived from bamboo using hydrothermal carbonization. The structural and textural morphology of the beads were studied using FTIR, XRD, SEM/EDS, BET and TGA. Activated hydrochar showed a rough surface with irregular spherical shaped structure.

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Fresh water is one of the essential sources of life, and its requirement has increased in the past years due to population growth and industrialization. Industries use huge quantities of fresh water for their processes, and generate high quantities of wastewater rich in organic matter, nitrates, and phosphates. These effluents have contaminated the freshwater sources and there is a need to recycle this wastewater in an ecologically harmless manner.

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The food packaging industries are facing the challenge of food waste generation. This can be addressed through the use of edible coating materials. These coatings aid in extending the shelf life of food products, reducing waste.

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In the current study, an attempt was made to synthesize coffee husk (CH) activated carbon by chemical modification approach (sulphuric acid-activated CH (SACH) activated carbon) and was used as a valuable and economical sorbent for plausible remediation of Methylene blue (MB) dye. Batch mode trials were carried out by carefully varying the batch experimental variables: SACH activated carbon (SACH AC) dosage, pH, initial dye concentration, temperature, and contact time. The optimum equilibrium time for adsorption by SACH activated carbon was obtained as 60 min, and the maximum adsorption took place at 30 °C.

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The electrochemical degradation of alizarin red dye was studied using bismuth oxyhalide attached to bismuth vanadate nanocomposite synthesized via a simple solvothermal method. The electrochemical degradation of alizarin red dye was treated at current densities of 3 and 5 mA cm for 30 min under different supporting electrolyte mediums (NaCl and KCl). Also, the electrochemical degradation of BiOBr/BiVO electrode shows higher degradation percentages of 97 and 99 for NaCl and KCl electrolyte solutions, which are higher degradation percentages than pure BiVO electrode (88 and 91 for NaCl and KCl).

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Organochlorine pesticides (OCPs) have been used in agriculture, increasing crop yields and representing a serious and persistent global contaminant that is harmful to the environment and human health. OCPs are typically bioaccumulative and persistent chemicals that can spread over long distances. The challenge is to reduce the impacts caused by OCPs, which can be achieved by treating OCPs in an appropriate soil and water environment.

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Palm oil fuel ash (POFA) has limited use as a fertilizer, while contribute effectively to the environmental contamination and health risks. Petroleum sludge poses a serious effect on the ecological environment and human health. The present work aimed to present a novel encapsulation process with POFA binder for treating petroleum sludge.

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A co-precipitation technique has been used to prepare Bismuth tungstate nanoparticles (BiWO) for electrochemical capacitors and electrochemical sensing of Ascorbic acid (AA). Using a scanning rate of 10 mV s , the electrode was performed as the pseudocapacitance behavior and the specific capacitance to be up to 677 Fg at 1 A/g. BiWO versus Glassy carbon electrode (GCE) was also used to study the behavior of the BiWO modified electrodes in detecting ascorbic acid.

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Article Synopsis
  • This study analyzes the electrochemical detection of two antibiotics, SMX and TMP, in tablet form using a modified glassy carbon electrode with a nanocomposite of graphene oxide and Zinc Oxide Quantum Dots (GO-ZnO QDs).
  • The research utilized techniques such as cyclic voltammetry and square wave voltammetry to assess the electrodes' effectiveness, revealing varied detection potentials for each electrode type.
  • Results showed that GO-based electrodes performed better in detecting SMX and TMP, with low detection limits, indicating potential for biomedical applications in real-time monitoring of these drugs in tablet formulations.
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A biocatalytic membrane offers an ideal alternative to the conventional treatment process for the removal of toxic pentachlorophenol (PCP). The limelight of the study is to utilize superparamagnetic iron oxide nanoparticles (SPIONs) incorporated (poly (methyl vinyl ether-alt-maleic acid) (PMVEAMA) and poly (ether - ether) sulfone (PEES)) membrane for immobilization of laccase and its application towards the removal of PCP. In regard to immobilization of Tramates versicolor laccase onto membranes, 5 mM glutaraldehyde with 10 h cross-linking time was employed, yielding 76.

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Article Synopsis
  • Decarbonization is increasingly vital due to growing energy needs and declining oil supplies, and biotechnology offers a cost-effective way to reduce carbon emissions.
  • Bioenergy generation stands out as an eco-friendly method for addressing climate change in the energy sector and is expected to significantly lower global carbon output.
  • The review emphasizes innovative biotechnological strategies, the role of engineered microbes in CO mitigation, and highlights the production of biohydrogen and biomethane through anaerobic digestion, while discussing the potential for creating various bioproducts from CO conversions.
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Heavy metals, dyes and pharmaceutical pollutants in water environment are considered as serious threat to the human and animal health globally. Rapid development of industrialization and agricultural activities are the major source for eliminating the toxic pollutants into the aquatic environment. Several conventional treatment methods have been suggested for the removal of emerging contaminants from wastewater.

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The progress of versatile chemicals and bio-based fuels using renewable biomass has gained ample importance. Furfural and 5-hydroxymethylfurfural are biomass-derived compounds that serve as the cornerstone for high-value chemicals and have a myriad of industrial applications. Despite the significant research into several chemical processes for furanic platform chemicals conversion, the harsh reaction conditions and toxic by-products render their biological conversion an ideal alternative strategy.

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