Efficient alkane hydroxylation catalysis of nickel(ii) complexes with oxazoline donor containing tripodal tetradentate ligands.

Tris(oxazolynylmethyl)amine TOA (where R denotes the substituent groups on the fourth position of the oxazoline rings) complexes of nickel(ii) have been synthesized as catalyst precursors for alkane oxidation with meta-chloroperoxybenzoic acid (m-CPBA). The molecular structures of acetato, nitrato, meta-chlorobenzoato and chlorido complexes with TOA have been determined using X-ray crystallography. The bulkiness of the substituent groups R affects the coordination environment of the nickel(ii) centers, as has been demonstrated by comparison of the molecular structures of chlorido complexes with TOA and TOA.