Nonclassical Pathways: Accelerated Crystal Growth of Sodium Hexafluorosilicate Microrods via Nanoparticle-Assisted Processes with 0D Silicon Quantum Dots.

Nonclassical crystallization represents an innovative pathway that utilizes nanoparticles, enabling the generation of single crystals, going beyond a classical mechanism dependent on atoms, ions, or molecules. Our investigation has revealed hierarchical structures emerging via the aggregation and fusion of primary silicon quantum dots (SiQDs). In contrast to the classical ion-by-ion crystallization process, the primary SiQDs initially undergo aggregation, followed by fusion and their subsequent crystallization, leading to the ultrafast crystal growth of sodium hexafluorosilicate (SHFS) microrods with diverse morphologies.

Insight into the photophysics of strong dual emission (blue & green) producing graphene quantum dot clusters and their application towards selective and sensitive detection of trace level Fe and Cr ions.

Graphene-nanostructured systems, such as graphene quantum dots (GQDs), are well known for their interesting light-emitting characteristics and are being applied to a variety of luminescence-based applications. The emission properties of GQDs are complex. Therefore, understanding the science of the photophysics of coupled quantum systems (like quantum clusters) is still challenging.

Highly Responsive Ultraviolet Sensor Based on ZnS Quantum Dot Solid with Enhanced Photocurrent.

Detection of visible blind UV radiation is not only interesting but also of technologically important. Herein, we demonstrate the efficient detection of UV radiation by using cluster like ZnS quantum dot solid nanostructures prepared by simple reflux condensation technique. The short-chain ligand 3-mercaptopropionic acid (MPA) involved in the synthesis lead to the cluster like formation of ZnS quantum dots into solids upon prolonged synthesis conditions.

Graphene Quantum Dot Solid Sheets: Strong blue-light-emitting & photocurrent-producing band-gap-opened nanostructures.

Graphene has been studied intensively in opto-electronics, and its transport properties are well established. However, efforts to induce intrinsic optical properties are still in progress. Herein, we report the production of micron-sized sheets by interconnecting graphene quantum dots (GQDs), which are termed 'GQD solid sheets', with intrinsic absorption and emission properties.