Self-organized spreading of droplets to fluid toroids.

Hypothesis: Mixing of a chemical trigger of lower surface tension into a microdroplet with relatively higher surface tension can cause a rapid spreading of the droplet on a liquid-sublayer to form a host of metastable liquid morphologies such as sheets, toroids, threads, or droplets. Subsequently, such metastable fluidic objects break into a collection of droplets to form microemulsions.

Experiments: Introduction of surfactant loaded water or long-chain alcohols into an oleic acid microdroplet stimulate a rapid spreading of the same on a water sublayer, which helps in the formation of a metastable liquid sheet connected to a liquid toroid.

Microfluidic Schottky-junction photovoltaics with superior efficiency stimulated by plasmonic nanoparticles and streaming potential.

A droplet energy harvester (DEH) composed of aqueous salt solution could generate electrical energy from light when placed on a metal-semiconductor Schottky-junction emulating the principles of electrochemical photovoltaics (ECPV). The maximum potential difference generated was ∼95 mV under sun, which was enhanced by ∼1.5 times after the addition of gold nanoparticles (AuNPs) in the droplet because of the generation of additional charge carriers from the localized surface plasmon resonance (LSPR).

Electric field mediated spraying of miniaturized droplets inside microchannel.

We report a facile and noninvasive way to disintegrate a microdroplet into a string of further miniaturized ones under the influence of an external electrohydrodynamic field inside a microchannel. The deformation and breakup of the droplet was engendered by the Maxwell's stress originating from the accumulation of induced and free charges at the oil-water interface. While at smaller field intensities, for example less than 1 MV/m, the droplet deformed into a plug, at relatively higher field intensities, e.

Discrete electric field mediated droplet splitting in microchannels: Fission, Cascade, and Rayleigh modes.

Numerical simulations supplemented by experiments together uncovered that strategic integration of discrete electric fields in a non-invasive manner could substantially miniaturize the droplets into smaller parts in a pressure driven oil-water flow inside microchannels. The Maxwell's stress generated from the electric field at the oil-water interface could deform, stretch, neck, pin, and disintegrate a droplet into many miniaturized daughter droplets, which eventually ushered a one-step method to form water-in-oil microemulsion employing microchannels. The interplay between electrostatic, inertial, capillary, and viscous forces led to various pathways of droplet breaking, namely, fission, cascade, or Rayleigh modes.