Methyl is crucial in plasma-assisted hydrocarbon chemistry, making precise in situ imaging essential for understanding various plasma applications. Its importance in methane chemistry arises from its role as a primary byproduct during the initial phase of methane dehydrogenation. Detecting the CH radical is challenging due to its high reactivity and the prevalence of strongly pre-dissociative electronically excited states.
View Article and Find Full Text PDFA thermographic phosphor's decay time distribution over its temperature-sensitive range was retrieved with the Maximum Entropy Method (MEM). A decay time distribution consists of a range of decay times, each with an associated weighting for the decay time component's prevalence in the analyzed decay curve. With the MEM, significant decay time contributions of a decay curve have high weighting and are therefore found as peaks in the decay time distribution, where the width and peak value are correlated with the relative weight of the decay time components.
View Article and Find Full Text PDFFluorescence lifetime determination has proven to be useful, e.g. identification of molecules, quantitative estimation of species concentration and determination of temperatures.
View Article and Find Full Text PDFPhotomultiplier tube (PMT) nonlinearities relevant for single shot high-speed lifetime phosphor thermometry were investigated by simulating decay curves with a light emitting diode (LED) at repetition rates between 1 Hz and 10 kHz. The PMT gain, LED decay time, and background radiant flux were also varied to investigate their impact on the measured decay time error. Errors in the measured decay time due to nonlinear PMT performance lead to temperature measurement errors; therefore, having the measured decay time sensitive to only phosphor temperature is highly valuable for more reliable temperature measurements.
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