Compact two-step laser time-of-flight mass spectrometer for in situ analyses of aromatic organics on planetary missions.

Rationale: A miniature time-of-flight mass spectrometer measuring 20 cm in length has been adapted to demonstrate two-step laser desorption/ionization (LDI) in a compact instrument package for enhanced organics detection. Two-step LDI decouples the desorption and ionization processes, relative to traditional LDI, in order to produce low-fragmentation mass spectra of organic analytes. Tuning the UV ionization laser energy would allow control of the degree of fragmentation, which might enable better identification of constituent species.

Arrayed time-of-flight mass spectrometry for time-critical detection of hazardous agents.

The design and operation of an arrayed time-of-flight (TOF) mass spectrometer for simultaneous data acquisition from multiple samples is described. Versions of the instrument employ sets of two or four linear or reflectron mass analyzers. They are housed in the same vacuum chamber and utilize the same laser for ion desorption.