In this work, the synthesis of visible light sensitive copper sulfide (CuS) nanoparticles and their composites with carbon nanotubes (T-CuS) a solvothermal technique is reported. The synthesized nanoparticles (NPs) and their composites were significantly characterized by powder X-ray diffraction (PXRD), scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, UV-vis spectroscopy, photoluminescence (PL) spectroscopy and thermogravimetric analysis (TGA). The effect of carbon nanotubes (CNTs) on the crystallinity, microstructures, photo-absorption, photo-excitation, thermal stability and surface area of CuS was investigated.
View Article and Find Full Text PDFThe synthesis of solar-light-responsive zinc telluride (ZnTe) nanoparticles and their composite with reduced graphene oxide (rGO-ZnTe) via a simple hydrothermal reaction is reported. The synthesized nanostructures were comprehensively characterized by a combination of X-ray diffraction and photoelectron spectroscopy, electron microscopy, UV-vis spectroscopy, photoluminescence spectroscopy and thermogravimetric analysis. The effects of graphene oxide on the crystallinity, microstructure, photo-excitation, light absorption, surface area and thermal stability of ZnTe were studied.
View Article and Find Full Text PDFA novel fluorophore (HL) [1-(()-(quinolin-8-ylimino)methyl)anthracen-2-ol] using a suitably designed anthrol and quinoline derivative was synthesized and well characterized. Then, two Re(I) complexes with the -[Re(CO)] moiety were prepared with the ligand under different reaction conditions. Both the complexes [Re(L)(CO)] (1) and [Re(HL)(CO)Cl] (2) absorbed in the visible region.
View Article and Find Full Text PDFMedicinal plants are a source of phytochemicals and they are used for the treatment of several oxidative stress-related or other diseases for their effectiveness, low toxicity and easy availability. Five traditionally used and less characterized herbaceous weeds of West Bengal, India, namely, , , , and , were investigated for the current research study. Aqueous and 70% ethanolic extracts of the leaves were analyzed for estimation of essential phytochemicals and to evaluate their antioxidant status, medicinal properties and cytotoxic effects.
View Article and Find Full Text PDF[Pb(bdc)(aiz)] () and [Pb(bdc)(aiz)(MeOH)] () (Hbdc = 1,4-benzene dicarboxylic acid, aiz = ()-'-(thiophen-2-ylmethylene)isonicotinohydrazide) have been synthesized, and structural characterization has been established by X-ray analysis and thermogravimetric analysis (TGA). Here, bdc links two Pb(II) centers and the aiz ligand binds the metal centers in two different manners: chelating and monodonating. Thus, polymerizations have taken place from the combination of mixed ligand system.
View Article and Find Full Text PDFThe opto-electronic properties of an X-ray characterized, end-to-end azide bridged cobalt(iii)-sodium complex, [(N)CoLNa(N)] , have been investigated in detail. The complex is found to be a direct semiconductor material as confirmed by determining the band gap of this complex by experimental as well as theoretical studies. The complex has also been used to construct a photosensitive Schottky device.
View Article and Find Full Text PDFOrganic-inorganic hybrid perovskite has appeared as one of the leading materials for realizing solution-based high-performing optoelectronic devices. The charge transport properties in this class of material are quite intriguing and still need to be carefully investigated. The temperature-dependent electrical property of methylammonium lead iodide (CHNHPbI) has been investigated by employing positron annihilation spectroscopy (PAS), which unambiguously reveals the gradual formation of open volume defects with the enhancement in temperature.
View Article and Find Full Text PDF