ZnO is a potential candidate for providing an economic and environmentally friendly substitute for energy storage materials. Therefore, in this work, Fe-doped ZnO nanostructures prepared using the microwave irradiation procedure were investigated for structural, morphological, magnetic, electronic structural, specific surface area and electrochemical properties to be used as electrodes for supercapacitors. The X-ray diffraction, high-resolution transmission electron microscopy images, and selective-area electron diffraction pattern indicated that the nanocrystalline structures of Fe-doped ZnO were found to possess a hexagonal wurtzite structure.
View Article and Find Full Text PDFHerein, we have reported a novel strategy for improving the electrochemical performance of laser-induced graphene (LIG) supercapacitors (SCs). The LIG was prepared using a CO laser system. The polyimide polymer was the source material for the fabrication of the LIG.
View Article and Find Full Text PDFMagnetic nanoparticles of NiFeO were successfully prepared by utilizing the sol-gel techniques. The prepared samples were investigated through various techniques such as X-ray diffraction (XRD), transmission electron microscopy (TEM), dielectric spectroscopy, DC magnetization and electrochemical measurements. XRD data analysed using Rietveld refinement procedure inferred that NiFeO nanoparticles displayed a single-phase nature with face-centred cubic crystallinity with space group Fd-3m.
View Article and Find Full Text PDFTo meet the growing demand for efficient and sustainable power sources, it is crucial to develop high-performance energy storage systems. Additionally, they should be cost-effective and able to operate without any detrimental environmental side effects. In this study, rice husk-activated carbon (RHAC), which is known for its abundance, low cost, and excellent electrochemical performance, was combined with MnFeO nanostructures to improve the overall capacitance of asymmetric supercapacitors (ASCs) and their energy density.
View Article and Find Full Text PDFCeXO (X: Fe, Mn) nanoparticles, synthesized using the coprecipitation route, were investigated for their structural, morphological, magnetic, and electrochemical properties using X-ray diffraction (XRD), field emission transmission electron microscopy (FE-TEM), dc magnetization, and cyclic voltammetry methods. The single-phase formation of CeO nanoparticles with FCC fluorite structure was confirmed by the Rietveld refinement, indicating the successful incorporation of Fe and Mn in the CeO matrix with the reduced dimensions and band gap values. The Raman analysis supported the lowest band gap of Fe-doped CeO on account of oxygen non-stoichiometry.
View Article and Find Full Text PDFDifferent rare-earth (RE) metal-oxides nano-particles (NPs) viz. Samarium (III) oxide (SmO), Neodymium (III) oxide (NdO), and Gadolinium (III) oxide (GdO) were synthesized using co-precipitation route, and investigated by structural, optical, and morphological studies. Findings and supporting studies were presented to understand the role of RE-metal-oxides NPs as photo-anode material for dye sensitized solar cells (DSSCs) applications.
View Article and Find Full Text PDFIn the present work, Cu-doped ZnO nanostructures (Cu% = 0, 1, 5) have been prepared using microwave-assisted chemical route synthesis. The synthesized nanostructures were investigated through structural, morphological, optical, and magnetic characterizations. The results of the X-ray diffraction (XRD), high resolution transmission electron microscopy (HR-TEM), and selective area electron diffraction (SAED) patterns confirmed that all of the samples exhibit the single-phase polycrystalline hexagonal crystal structure.
View Article and Find Full Text PDFThe nanoparticles of CeO, CeFeO, and CeFeCuO were synthesized using the co-precipitation-synthesis technique. The effect of co-doping of Fe and Cu on structural, optical, and magnetic properties as well as specific capacitance have been studied using X-ray diffraction (XRD), scanning-electron microscopy (SEM), UV-visible spectroscopy, Raman spectroscopy, dc magnetization, and electrochemical measurements at room temperature. The results of the XRD analysis infer that all the samples have a single-phase nature and exclude the formation of any extra phase.
View Article and Find Full Text PDFBiFe1−xCrxO3, (0 ≤ x ≤ 10) nanoparticles were prepared through the sol−gel technique. The synthesized nanoparticles were characterized using various techniques, viz., X-ray diffraction, high-resolution field emission scanning electron microscopy (HRFESEM), energy dispersive spectroscopy (EDS), UV−Vis absorption spectroscopy, photoluminescence (PL), dc magnetization, near-edge X-ray absorption spectroscopy (NEXAFS) and cyclic voltammetry (CV) measurements, to investigate the structural, morphological, optical, magnetic and electrochemical properties.
View Article and Find Full Text PDFEnhanced visible light photocatalytic activity of Gd-doped CeO nanoparticles (NPs) is experimentally demonstrated, whereas there are very few reports on this mechanism with rare earth doping. All-pure and Gd-doped CeO NPs are synthesized using a coprecipitation method and characterized using X-ray diffraction (XRD), absorption spectroscopy, surface-enhanced Raman Spectroscopy (SERS), X-ray photoelectron spectroscopy (XPS), and superconducting quantum interference device (SQUID). The effect of Gd-doping on properties of CeO is discussed along with defects and oxygen vacancies generation.
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