Publications by authors named "Saswata Rabi"

The isomeric ligand L, a saturated analogue of 2,9-C-meso-Me[14]diene, on reflux with excess acrylonitrile afforded 1,8-N-pendant cyanoethyl derivative L. Interaction of L with cadmium(II) perchlorate, nitrate, acetate, and chloride salts produced six coordinated octahedral compounds, [Cd(L) (ClO)]∙2HO, [Cd(L) (NO)], [Cd(L) (CHCOO)], and [Cd(L)Cl], respectively. Further, axial substitution reactions between [Cd(L) (ClO)]∙2HO and KI, KBr, KCl, KSCN, and NaNO in a 1:2 ratio yielded six coordinated octahedral compounds, [Cd(L)I]∙HO, [Cd(L)Br]∙2HO, [Cd(L)Cl(ClO)]∙2HO, [Cd(L) (NCS)]∙HO, and [Cd(L) (NO) (ClO)]∙2HO, respectively.

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The title Cu macrocyclic complex salt tetra-hydrate, [Cu(CHNO)](CHO)·4HO, sees the metal atom located on a centre of inversion and coordinated within a 4 + 2 (NO) tetra-gonally distorted coordination geometry; the N atoms are derived from the macrocycle and the O atoms from weakly associated [3.2048 (15) Å] acetate anions. Further stability to the three-ion aggregate is provided by intra-molecular amine-N-H⋯O(carboxyl-ate) hydrogen bonds.

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