Synthesis and functional mechanism evaluation of novel polymer-graphene oxide-biochar nanocomposite for efficient removal of diethyl phthalate.

Phthalates, categorized as a main constituent of endocrine-disrupting chemicals (EDCs), are present in polymeric products. These substances can enter the environment through several pathways, including improper handling, which leads to their presence in toilet water, floor washings, surface runoff, and landfill leachate. This study focuses on the performance analysis of nanocomposite materials made of polymer (polypyrrole), quasi-metal (graphene oxide), and biochar (from palmyra seed) for the elimination of diethyl phthalates (DEP) from aqueous environments.

Sustainable development and analysis of a novel bio-derived (biochar) nanocomposite for the remediation of carbamazepine from aqueous solution.

The presence of pharmaceutical compounds in aqueous environments has become a growing concern due to their potential adverse effects on ecosystems and human health. In this work, synthesis of a novel bio based nanocomposite using a biowaste, palm seed is employed for the preparation of biochar. The bio derived nanocomposite consist of polypyrrole (Ppy), graphene oxide (GO), and biochar, is employed for the Carbamazepine (CBZ) removal.

Bio-fabrication of porous magnetic Chitosan/FeO nanocomposite using Azolla pinnata for removal of chromium - Parametric effects, surface characterization and kinetics.

In this research, a novel porous nanocomposite, namely Chitosan-iron-oxide @ Azolla pinnata nanocomposite, has been synthesized by co-precipitation and hydrothermal method. The effect of process parameter on adsorption process was investigated. Batch removal of chromium (Cr) was optimized with respect to solution pH, batch stirring time, sorbent dose, initial chromium concentration and temperature.

Potential risks and approaches to reduce the toxicity of disinfection by-product - A review.

Water contamination through anthropogenic and industrial activities has led to the emergence and necessity of disinfection methods. Chlorine and bromine gases, often used to disinfect water, resulted in the by-product formation by reacting with organic matter. The Disinfectant by-products (DBP) led to the formation of Trihaloaceticacid (TAA), Trihalomethane (THM), and other minor components.

Removal of lead ions using OA-FeO magnetic nanoparticles-based pickering emulsion liquid membrane: process optimization using box-behnken response surface methodology.

The purpose of this study is to explore the pickering emulsion liquid membrane (PELM) performance for removing divalent lead ions (Pb II) from aqueous solution. In the present work, the membrane phase was prepared by dissolving methyltrioctylammonium chloride (Aliquat 336) with Mahua oil and adding oleic acid coated-ferrosoferric oxide (OA-FeO) as magnetic nanoparticles. Experimental investigation on percentage removal of lead ions was carried out by studying the influencing process parameters such as pH, agitation speed, stripping concentration, initial feed concentration, surfactant concentration, treat ratio, M/S ratio and carrier concentration.

Application of a polymer-magnetic-algae based nano-composite for the removal of methylene blue - Characterization, parametric and kinetic studies.

The potential ability of synthesized PPy-FeO-SW nano-composite to remove Methylene Blue (MB) from synthetic textile dye solution was investigated under batch conditions. Through parametric studies, the influence of process parameters namely solution pH, on the effective performance of nano-composite was studied. PPy - FeO- SW nano-composite removed 99.

Adsorptive potential of iron oxide based nanocomposite for the sequestration of Congo red from aqueous solution.

The ability of polypyrrole-Iron oxide-seaweed nanocomposite has been tested for the removal of congo red from aqueous solution. The characteristics of nanocomposite after adsorption of Congo red (CR) have been analyzed. FTIR results authorized the involvement of various functional groups in the adsorption of CR.

Performance evaluation of polymer-marine biomass based bionanocomposite for the adsorptive removal of malachite green from synthetic wastewater.

In this experimental investigation, feasibility and performance of a polymer hybrid bio-nano composite were evaluated to remove malachite green (MG) under controlled environment conditions. The polymer hybrid bio-nanocomposite was characterized using FTIR, SEM and EDS. The influence of operating variables, namely effect of pH (2-11), nanocomposite dosage (20-100 mg), initial MG concentration (10- 200 mg/L), contact time (10-120 min) and temperature (298-318 K) were explored.

Surface modified polymer-magnetic-algae nanocomposite for the removal of chromium- equilibrium and mechanism studies.

The present work explains the sorption ability of a novel nano-composite, Polypyrrole -iron oxide-seaweed (PPy - FeO - SW), for Cr(VI) removal. The influence of operating parameters, namely pH, contact time, nanocomposite dosage, initial Chromium concentration and operating temperature, on the hexavalent chromium removal was studied. The novel nano-composite was analyzed using FTIR, SEM and EDS to confirm the sorption of Cr(VI) and to understand the mechanism of sorption.

Facile synthesis and characterization of polypyrrole - iron oxide - seaweed (PPy-FeO-SW) nanocomposite and its exploration for adsorptive removal of Pb(II) from heavy metal bearing water.

Lead is a widely used heavy metal which is highly toxic to kidney, nervous system and reproductive system. A special featured polypyrrole based adsorbent, with admirable salinity confrontation, environmental stability and reusability, was engaged to remove lead ions from aqueous solution. The advantages of using polypyrrole based adsorbent for heavy metal removal are: ease of synthesis, biocompatibility and high metal selectivity.

Mineral content of water and food in fluorotic villages and prevalence of dental fluorosis.

The fluoride (F), calcium (Ca), magnesium (Mg), zinc (Zn), copper (Cu), and phosphorus (P) content in potable water and food samples from endemic and nonendemic villages for fluorosis were analyzed. It was found that the F content in water was significantly higher (p<0.01) in endemic villages (4.

Introduction of red palm oil into the 'ready to eat' used supplementary feeding programme through ICDS.

Children attending the anganwadi centres were fed with Ready to eat (RTE) food containing 2g of Red Palm Oil (RPO). Daily children's attendance, their participation in the feeding programme, quantity of food supplement consumed were recorded. Heights, weights, clinical signs of vitamin A deficiency and morbidity pattern of the beneficiary children were assessed.

Glycemic index of grain amaranth, wheat and rice in NIDDM subjects.

Glycemic index of grain amaranth, wheat and rice preparations was studied in non-insulin dependent diabetic subjects. Diets containing 50 g carbohydrate equivalent were given and post-prandial blood glucose estimated at different intervals. Glycemic index calculated for different experimental diets showed that GI of amaranth-wheat composite flour diet (25:75) was the least (65.

Hypocholesterolemic effect of amaranth seeds (Amaranthus esculantus).

Hypocholesterolemic effect of amaranth seeds was studied in male wistar strain albino rats as against Bengal gram. The results showed that liver weights were significantly higher in animals with hypercholesterolemia inducing diet. Contrarily, weights of other organs like brain, kidney, testes and spleen showed higher weights with amaranth and bengal gram diets.

Interaction, functional relations and evolution of large and small subunits in Rubisco from prokaryota and eukaryota.

In early biological evolution anoxygenic photosynthetic bacteria may have been established through the acquisition of ribulose bisphosphate carboxylase-oxygenase (Rubisco). The establishment of cyanobacteria may have followed and led to the production of atmospheric oxygen. It has been postulated that a unicellular cyanobacterium evolved to cyanelles which were evolutionary precursors of chloroplasts of both green and non-green algae.

Transformation of the cyanobacterium Anacystis nidulans 6301 with the Escherichia coli plasmid pBR322.

Anacystis nidulans 6301 has been transformed in the light to ampicillin resistance with the plasmid pBR322. Permeaplasts prepared by 2-hr treatment of cells with lysozyme and EDTA are transformed with a 50-fold higher efficiency than that observed for cells. beta-Lactamase is present in A.

Inhibition of glycine oxidation by carboxymethoxylamine, methoxylamine, and acethydrazide.

Carboxymethoxylamine (amino-oxyacetate), methoxylamine, and acethydrazide are shown to be effective, although not completely specific, inhibitors of glycine oxidation by the isolated glycine decarboxylase multienzyme complex, mitochondria, protoplasts, and leaf discs from peas. The inhibition probably results from a reaction between these compounds and the pyridoxal 5-phosphate cofactor of the enzyme.

Extraction and partial characterization of the glycine decarboxylase multienzyme complex from pea leaf mitochondria.

Glycine decarboxylase has been successfully solubilized from pea (Pisum sativum) leaf mitochondria as an acetone powder. The enzyme was dependent on added dithiothreitol and pyridoxal phosphate for maximal activity. The enzyme preparation could catalyze the exchange of CO(2) into the carboxyl carbon of glycine, the reverse of the glycine decarboxylase reaction by converting serine, NH(4) (+), and CO(2) into glycine, and (14)CO(2) release from [1-(14)C]glycine.

Simultaneous oxidation of glycine and malate by pea leaf mitochondria.

Mitochondria isolated from pea leaves (Pisum sativum L.) readily oxidized malate and glycine as substrates. The addition of glycine to mitochondria oxidizing malate in state 3 diminished the rate of malate oxidation.

On the active species in bicarbonate stimulation of Hill reaction in thylakoid membranes.

At 5 degree C addition of CO2 or HCO3- to CO (HCO3-)-depleted thylakoids (containing 100 mM formate) initiates, within 10 s, the activation of the Hill reaction in light. In contrast to HCO3- addition, where there is a lag of 6-8 s, the activation by CO2 addition is almost instantaneous. With CO2, prior addition of carbonic anhydrase produces a lag of about 6 s that approaches the lag observed by the HCO3- addition.