Selective detection of salivary cortisol using screen-printed electrode coated with molecularly imprinted polymer.

A novel electrochemical sensor was developed for the detection of salivary cortisol levels. The sensor employs a combination of a molecularly imprinted polymer (MIP) and gold nanoparticles (AuNPs) that are electrodeposited onto a screen-printed electrode (SPE). The study utilised density functional theory and molecular docking techniques to determine the geometry of molecular orbitals, electrostatic potential energies, and binding energy of cortisol and the polymers.

Molecularly imprinted polymer-based electrochemical sensor for the determination of endocrine disruptor bisphenol-A in bovine milk.

Bisphenol A (BPA) contamination from food packaging material has been a major concern in recent years, due to its potential endocrine-disrupting effects on humans, especially infants and children. This paper reports the detection of BPA using an electrochemical sensor based on molecularly imprinted polymer (MIP). Electrochemically reduced graphene oxide coated glassy carbon electrode used for this study.

A NiCo-MOF nanosheet array based electrocatalyst for the oxygen evolution reaction.

Metal organic frameworks (MOFs) are excellent materials for energy storage and conversion. This report describes 2D metal-organic framework nanosheets as an electrocatalyst for the oxygen evolution reaction (OER) under alkaline conditions. An ultrathin nanosheet array of a NiCo-metal-organic framework was grown on nickel foam (NiCo-MOF/NF) by a one-step solvothermal method.

Influence of anellation in N-heterocyclic carbenes: novel quinoxaline-anellated NHCs trapped as transition metal complexes.

The synthesis, NMR-, and crystal structure data of novel electron-deficient quinoxaline anellated imidazol-2-ylidene precursors and complexes thereof are reported and compared with related less electron-withdrawing or non-anellated N-heterocyclic carbenes and complexes to illustrate anellation effects.

Anellated N-heterocyclic carbenes: 1,3-dineopentylnaphtho[2,3-d]imidazol-2-ylidene: synthesis, KOH addition product, transition-metal complexes, and anellation effects.

Two novel anellated N-heterocyclic carbenes (NHC), 1,3-dineopentylnaphtho[2,3-d]imidazol-2-ylidene, and 1,3-dineopentyl-2-ylido-imidazolo[4,5-b]pyridine were obtained by reduction of the respective thiones with potassium, the former also by deprotonation of the corresponding naphthimidazolium hexafluorophosphate by using excess KH in THF. The use of equimolar amounts of KH provided an unexpected formal addition product of this NHC with KOH. X-ray crystal structure analysis of the adduct provided evidence for a distorted tetrameric N-heterocyclic alkoxide, stabilized by two THF molecules.