Controlling Molecular Photoisomerization in Photonic Cavities through Polariton Funneling.

Strong coupling between photonic modes and molecular electronic excitations, creating hybrid light-matter states called polaritons, is an attractive avenue for controlling chemical reactions. Nevertheless, experimental demonstrations of polariton-modified chemical reactions remain sparse. Here, we demonstrate modified photoisomerization kinetics of merocyanine and diarylethene by coupling the reactant's optical transition with photonic microcavity modes.

Accurate phase detection in time-domain heterodyne SFG spectroscopy.

Heterodyne detection is a ubiquitous tool in spectroscopy for the simultaneous detection of intensity and phase of light. However, the need for phase stability hinders the application of heterodyne detection to electronic spectroscopy. We present an interferometric design for a phase-sensitive electronic sum frequency generation (e-SFG) spectrometer in the time domain with lock-in detection.