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View Article and Find Full Text PDFAqueous solutions containing the nanoscale uranyl peroxide cage clusters U, [(UO)(O)(OH)], and UOx, [{(UO)(O)}(CO)], were monitored by in situ Raman spectroscopy during stepwise heating to 180 °C. In solutions containing U, clusters persist to 120 °C, although conversion of U to U, [(UO)(O)(OH)], occurs above 100 °C. UOx persisted in solutions heated to 150 °C, although partial conversion to smaller uranyl peroxide clusters species was observed beginning at 100 °C.
View Article and Find Full Text PDFThe evolutionary history of extant hominoids (humans and apes) remains poorly understood. The African fossil record during the crucial time period, the Miocene epoch, largely comprises isolated jaws and teeth, and little is known about ape cranial evolution. Here we report on the, to our knowledge, most complete fossil ape cranium yet described, recovered from the 13 million-year-old Middle Miocene site of Napudet, Kenya.
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