Shaping iron oxide nanocrystals for magnetic separation applications.

Iron oxide nanostructures are attractive for a variety of bio-related applications given their wide range of magnetic properties. Here, we report on the study of the magnetophoretic mobility of octapod-shaped nanocrystals, which we relate to stoichiometry, quality and elongation in the 111 direction of these cubic structures. This special morphology combines magnetocrystalline anisotropies, increases shape anisotropy and hinders the formation of an epitaxial wüstite-magnetite interface.

Magnetic hardening of Fe30Co70 nanowires.

3d transition metal-based magnetic nanowires (NWs) are currently considered as potential candidates for alternative rare-earth-free alloys as novel permanent magnets. Here, we report on the magnetic hardening of Fe30Co70 nanowires in anodic aluminium oxide templates with diameters of 20 nm and 40 nm (length 6 μm and 7.5 μm, respectively) by means of magnetic pinning at the tips of the NWs.

Room-temperature ferromagnetism in antiferromagnetic cobalt oxide nanooctahedra.

Cobalt oxide octahedra were synthesized by thermal decomposition. Each octahedron-shaped nanoparticle consists of an antiferromagnetic CoO core enclosed by eight {111} facets interfaced to a thin (∼ 4 nm) surface layer of strained Co3O4. The nearly perfectly octahedral shaped particles with 20, 40, and 85 nm edge length show a weak room-temperature ferromagnetism that can be attributed to ferromagnetic correlations appearing due to strained lattice configurations at the CoO/Co3O4 interface.