Manufacturing of copper micro-patterns is crucial in electronics for its utilization as high conductivity transparent conductive films (TCFs) and circuits. In the preparation process of current TCFs, a plethora of materials have emerged that can replace traditional indium tin oxide (ITO). However, even for the most promising metal-based nanowire materials, there are issues such as high cost, complex welding, and high contact resistance.
View Article and Find Full Text PDFThe development of efficient non-precious metal oxygen reduction reaction catalysts to replace Pt-based catalysts is of great significance to accelerate the commercial application of fuel cells. In this study, a hierarchical porous carbon oxygen reduction reaction catalyst with Fe/FeC/FeS@Fe-N-C active sites was developed a simple and efficient solid-phase synthesis method. The introduction of zinc inhibited the growth and agglomeration of the nanoparticles and induced the formation of active nitrogen species and porosity, thus boosting the catalytic activity.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
April 2021
It is of great importance to design a fluorescent sensor with high selectivity, sensitivity and large Stokes shift to zinc detection for environmental water sample and in vivo. Herein, A novel Zn fluorescent sensor with larger Stokes shift (110 nm) 1-((5-(4-(diphenylamino)phenyl)pyridine-2-imino)methyl)naphthalene-2-ol (abbr. TPA-PN) was designed and synthesized.
View Article and Find Full Text PDFThe severe dissolution of the cathode catalyst, caused by an undesired oxygen reduction reaction at the anode during startup and shutdown, is a fatal challenge to practical applications of polymer electrolyte membrane fuel cells. To address this important issue, according to the distinct structure-sensitivity between the σ-type bond in H and the π-type bond in O, we design a HD-Pt/TiN material by highly dispersing Pt on the TiN surface to inhibit the unwanted oxygen reduction reaction. The highly dispersed Pt/TiN catalyst exhibits excellent selectivity toward hydrogen oxidation and oxygen reduction reactions.
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