Structure-driven orientation of the high-spin-low-spin interface in a spin-crossover single crystal.

The orientation of the high-spin (HS)-low-spin (LS) macroscopic interface at the thermal transition of thin [{Fe(NCSe)(py)2}2(m-bpypz)] crystals is explained by considering the possible vanishing of the structural mismatch between the coexisting phases. The structural property which allows mismatch-free interfaces is characterized. The observed orientations of the interface and the tilt angle between the HS and LS domains are accurately reproduced by a two-dimensional continuous medium model, based on the structural data.