Publications by authors named "Santiago Garcia-Yuste"
Article Synopsis
- - The Tetrahedron approach is an innovative tool designed to evaluate the sustainability of human activities through a four-step process involving key parameter identification, evaluation, diagram construction, and global sustainability estimation.
- - It considers multiple sustainability dimensions—economic, social, and environmental—and has been applied in five case studies related to carbon capture and various production processes.
- - The Tetrahedron is shown to be effective and reliable for quantifying sustainability, offering a holistic, simple, and adaptable alternative to existing environmental assessment methods.
A novel Carbon Dioxide Utilization (CDU) approach from a relatively minor CO2 emission source, i.e., alcoholic fermentation processes (AFP), is presented.
View Article and Find Full Text PDFThe reactions of phosphido complexes [Nb(eta(5)-C(5)H(4)SiMe(3))(2)(L)(PPh(2))] [L = CO (1), CNxylyl (2), CNCy (3)] with alkynes have been carried out. The new diphenylphosphinoalkenyl niobocene complexes [Nb(eta(5)-C(5)H(4)SiMe(3))(2)(eta(1)-C-C(CO(2)CH(3))=C(R)PPh(2))(CO)] [R = H (4), CH(3) (5)] and [Nb(eta(5)-C(5)H(4)SiMe(3))(2)(eta(1)-C-C(CO(2)R)=C(CO(2)R)PPh(2))(CO)] [R = CH(3), (6), R = (t)Bu, (7)] were successfully synthesized by the reaction of with methyl propiolate (HC[triple bond]CCO(2)CH(3)) or methyl 2-butynoate (CH(3)C[triple bond]CCO(2)CH(3)) and dimethyl 2-butynedioate [(CH(3) O(2)C)C[triple bond]C(CO(2)CH(3))] or di(tert-butyl) 2-butynedioate [((t)BuO(2)C)C[triple bond]C(CO(2)(t)Bu)], respectively. However, reaction was not observed with more electron-rich alkynes.
View Article and Find Full Text PDFThe niobium phosphido complex [Nb(eta5-C5H4SiMe3)2-(CNXylyl)(PPh2)] (2) undergoes an unusual cycloaddition reaction with electron-deficient alkynes to give the novel five-membered heteroniobacycles [Nb(eta5-C5H4SiMe3)2(kappaC-C(=N(Xylyl))C(CO2Me)=C(R)PPh2-kappaP)] (R = H 3 and R = Me 4).
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