Lewis acid-catalyzed one-pot thioalkenylation of donor-acceptor cyclopropanes using generated dithiocarbamates and propiolates.

Lewis acid-catalyzed one-pot 1,3-thioalkenylation of donor-acceptor (D-A) cyclopropanes has been demonstrated employing generated dithiocarbamates (from amines and CS) as nucleophilic triggers and alkyl propiolates as electrophiles. This method addresses the limitations of previously known carbothiolation approach, eliminating the need for extra filtration prior to the subsequent trapping with electrophiles. The anticipated thioalkenylated products were obtained in good to excellent yields with a moderate to good / ratio.