Publications by authors named "Sanjay Attarde"

In the present research article we explore the synthesis method and adsorption capability of ZnFe oxides nanocomposites by using Pb as dopant. A conventional and simple batch adsorption method is selected and optimized. Pb@ZnFeO NCs were fabricated by facile method i.

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Article Synopsis
  • A new fluorescent receptor (receptor 3) was created to detect Cu(2+) and Zn(2+) ions selectively and sensitively in semi-aqueous environments.
  • The presence of Zn(2+) and Cu(2+) notably increased and decreased the fluorescence of receptor 3, distinct from other ions.
  • This receptor can form stable 1:1 complexes with Cu(2+) and Zn(2+), enabling its use as chemical inputs in a molecular level logic gate system.
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This study was conducted to determine the optimum extraction conditions for the effective separation and removal of Cu2+, Fe2+, and Fe3+ using N-benzoyl-n-phenylhydroxylamine (BPA) as an analytical reagent. An efficient liquid-liquid extraction method was developed for the separation and removal of Cu2+, Fe2+, and Fe3+ from environmental waste samples. In this method, BPA was used as a chelating agent and the effect of different parameters- including solvents, pH, stripping agents, extraction time, and the interference of other ions- on the quantitative removal of these metals was investigated.

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A malonohydrazide derivative bearing an imine and phenolic group was synthesized and had a high affinity and selectivity towards Zn(2+). The recognition properties of receptor 1 were evaluated using absorbance and fluorescence spectroscopy. The 1:1 stoichiometry of 1.

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A dipodal ligand 2,2'-((ethane-1,2-diylbis(azanediyl))bis(ethane-1,1-diyl))diphenol was synthesized through a condensation reaction and was characterized with IR, (1)H NMR, (13)C-NMR, and mass spectroscopy. The receptor 2 has shown marked enhancement in fluorescence intensity (emission signal at 341 nm) on binding with Zn(2+) as compared to other surveyed metal ions. The sensor has shown dramatic changes in dual channel fluorescence emission with λmax at 300 and 341 nm.

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A novel cell-permeable urea-linked dipodal naphthalene-based fluorescent receptor 1 (1,1'-(1,5,5-trimethyl-3-oxocyclohexane-1,2-diyl)bis(3-(naphthalen-2-yl)urea) was designed and synthesized. The cation recognition ability of 1 was evaluated with a library of metal ions in DMSO/H₂O (9:1, v/v). The receptor showed a selective chromogenic and fluorescent turn-off response towards Hg(2+) among the surveyed metal ions.

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A new non-natural receptor 2,2'-[benzene-1,2-diylbis(iminomethanediyl)]diphenol (4) was synthesized, and it is fluorogenic behaviour toward various metal ions were investigated. Receptor 4 exhibited pronounced fluorescence enhancement in the presence of Zn(2+), which can visually be discernible by an orchid fluorescence in compared to other metal ions. The receptor 4 shows high sensitivity and selectivity for Zn(2+) through changes in the fluorescence intensity based on chelation-enhanced fluorescence (CHEF).

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The noncyclic 2,2'-[ethane-1,2-diylbis (iminomethanediyl)]diphenol (4) fluorescent receptor bearing two amine and hydroxyl groups have been designed and investigated for their binding properties towards various cations. The fluorescent spectral measurements revealed that receptor 4 is a selective fluorescent sensor for Fe(3+) ions but not for metal ions such as Cr(3+), Mn(2+), Co(2+), Ni(2+), Cu(2+), Zn(2+), Cd(2+), Hg(2+), Pb(2+) and Bi(3+). The binding ability was confirmed with spectroscopic methods and density functional theory calculation (DFT).

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A dipodal fluorescent receptor, 2,2'-[ethane-1,2-diylbis(iminoethane-1,1-diyl)]diphenol (), with amine and hydroxyl moieties as binding sites has been synthesised and characterized with spectroscopic methods and single crystal X-ray techniques. The recognition of the anions with receptor was studied using UV-Vis and fluorescence spectroscopy. The (1)H-NMR spectroscopic and DFT studies revealed the distinct recognition of I(-) ions over the other surveyed anions.

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A new fluorescent receptor 1,1'-(4-methylbenzene-1,3-diyl)bis[3-(2-sulfanylphenyl)urea] (1) has been designed and synthesized. The receptor showed excellent selectivity for Fe(3+) in DMSO/H2O (8:2, v/v) solvent system over other commonly coexistent metal ions. The binding constant (Ka) of receptor with Fe(3+) was calculated to be 11,250 M(-1), 12,970 M(-1) and 12,970 M(-1) using Benesi-Hildebrand, Scatchard and Connor plot, respectively.

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A new chromogenic dipodal Zn2+ complex (4) bearing an amide group has been synthesized. The anion binding profile of this sensor was investigated with fluorescence and UV-Vis spectroscopy. The receptor 4 has high affinity for HSO4 − with a binding constant of 3.

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Urea based fluorescent chemosensor 1 was synthesized. Receptor 1 shows unique selectivity for the Fe(3+)ion and no such significant response was noticed with other metal ions (Cr(3+), Mn(2+), Co(2+), Ni(2+), Cu(2+), Zn(2+), Cd(2+), Hg(2+), Pb(2+) and Bi(3+)) in DMSO/H2O (50:50,v/v) semi-aqueous solution. The binding features have been established by absorption and fluorescence spectroscopic methods.

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A pyridine based imine-linked chemosensor has been synthesized and evaluated its binding affinity with library of transition metal ions. It has prominent selectivity towards Pb among other metal ions in DMF/HO (9:1, v/v) solvent system. The 1:1 stoichiometric was confirmed by job's plot and has a binding constant (K) = 5.

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Indoor air pollution is an ongoing problem in developing countries. Respiratory diseases are common worldwide in rural communities. This study was undertaken to estimate the respirable particulate matter (PM10) concentrations emitted from cooking fuels and their effects on the respiratory health of the rural population of Jalgaon district.

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The workplace environment affects the health of workers. Unhygienic conditions are observed in the workplace environment of flour mills as fine organic flour dust gets airborne in the indoor environment of the flour mills. The present work was undertaken to study the health problems related to the workplace environment of flour mill workers.

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In India, the traditional methods are used for urban solid waste management. These practices are associated with degradation of the urban environment Hence, an environmentally sound garbage management system is required for the urban waste management. The concept of waste minimization needs to be adopted in such systems.

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The ambient air quality monitoring was carried during the May 2003 to April 2004 along the (NH-6) passing through Jalgaon city. The average concentration of SOx 64 microg/m3, NOx 58 microg/ m3, particulates (> 10 micro) 515 microg/m3 and respirable dust particulates 224 microg/m3 was reported at Prabhat during the study period (May 2003-April 2004). This location represents the major highway crossings (four) in the study area.

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