Immobilization of a trimeric ruthenium cluster in mesoporous chromium terephthalate and its catalytic application.

Molecular trimeric ruthenium carboxylate clusters (Ru clusters) have been introduced into the pore channels of mesoporous metal-organic framework chromium terephthalate [MIL-101(Cr)] by employing a facile two-step post-synthetic strategy in which diamine hooks anchored on the framework metal nodes of the MOF are used to covalently immobilize the Ru clusters. The catalytic activity of the isolated Ru clusters in the pore channels of the MOF was significantly improved compared to the bulk counterpart.

Ag-exchanged mesoporous chromium terephthalate with sulfonate for removing radioactive methyl iodide at extremely low concentrations in humid environments.

The development of efficient adsorbents to remove radioactive methyl iodide (CHI) in humid environments is crucial for air purification after pollution by nuclear power plant waste. In this work, we successfully prepared a post-synthetic covalent modified MIL-101 with a sulfonate group followed by the ion-exchange of Ag (I), which is well characterized by diffuse reflectance FT-IR spectroscopy, X-ray photoelectron spectroscopy (XPS) and the hydrophobic index (HI). After modification of the MOFs, we applied functionalized MIL-101 obtained by either one-pot synthesis (MIL-101-SOAg) or a post-synthetic modification process (MIL-101-RSOAg, R = NH(CH)) to remove the CHI at an extremely low concentration (0.

Molecular Encapsulation of Trimeric Chromium Carboxylate Clusters in Metal-Organic Frameworks and Propylene Sorption.

Oxo-bridged trimeric chromium acetate clusters [Cr O(OOCCH ) (H O) ]NO have been encapsulated for the first time in the mesoporous cages of the chromium terephthalate MIL-101(Cr). The isolated clusters in MIL-101(Cr) have increased affinity towards propylene compared to propane, due to generation of a new kind of pocket-based propylene-binding site, as supported by DFT calculations.