Factors controlling methylmercury concentration in soils of Northern Poland.

Soil acts as storage for many toxic substances, including mercury and its compounds. However, in addition to its storage function, soil can also be a source of many substances to the aquatic environment. Methylmercury (MeHg) is one of the most toxic form of mercury (Hg) present in the environment.

The impact of global climate changes on trace and rare earth elements mobilization in emerging periglacial terrains: Insights from western shore of Admiralty Bay (King George Island, Antarctic).

In the rapidly changing climate, the biogeochemical behaviours of trace elements and Rare Earth Elements (REEs) in emerging periglacial environments assumes profound importance. This study provides pivotal insights into this dynamic by investigating the Antarctic's response to global climate change. The bedrock of King George Island is rich in REEs, with the presence of trace metals (TEs), with the highest concentrations of metals found in ornithogenic soil (∑REE 84.

Distribution of Cs in the marine environment from King George Island (Southern Shetlands, maritime Antarctica).

The article presents data on the activity of the radionuclide Cs in seawater, sediment, macroalgae, and zoobenthos from different locations in Admiralty Bay, King George Island, maritime Antarctica. The activity of Cs in the macrophytobenthos remained relatively stable across species, oscillating at the level of 1 Bq kgdw. However, a few individuals exhibited higher activity, particularly at stations closer to the glacier front.

Uptake and trophic transfer of selenium into phytoplankton and zooplankton of the southern Baltic Sea.

Selenium (Se) is an essential trace element and displays a narrow range of concentration between essentiality and toxicity. Se plays an important role in ameliorating mercury toxicity in organisms. Despite this there are only a few reports concerning Se concentration in plankton, the first link in the trophic chain that determines the uptake and transfer of Se to subsequent trophic levels.

Assessing the present levels of Cs in the remote ecosystem of Bjornoya (South Svalbard).

The remoteness and small size of Bjornoya (S Svalbard) make the island one of the most unreachable places in the Arctic. Limited accessibility contributes to still-existing knowledge gap on isotope accumulation in compartments of its ecosystem. Therefore, in this study we aimed to investigate the current concentration of Cs in the terrestrial samples of vascular plants, cryptogams, and soil collected on Bjornoya in 2021.

Mercury and methylmercury in birds and marine mammals inhabiting the coastal zone of the two King George Island's bays: Admiralty and King George Bay (maritime Antarctic).

The Antarctic is particularly sensitive to mercury (Hg) pollution and even low levels of Hg may cause significant damage in this fragile environment. The aim of this study was to investigate routes of mercury and methylmercury (MeHg) elimination by animals inhabiting the maritime Antarctic. The results showed that organisms at the highest trophic level (elephant seal) have the highest concentrations of THg and MeHg in both excrement and fur samples.

Distribution of Sr and Cs in biotic and abiotic elements of the coastal zone of the King George Island (South Shetland Archipelago, Antarctic Peninsula).

For many years Antarctic ecosystems have been considered pristine, however recent studies, including our results, contradict this assumption. Our comprehensive study on the activity of anthropogenic radioisotopes (Cs and Sr) in the most common species of green algae, bryophytes, lichens, and vascular plants, as well as soil and guano samples collected over a large area on King George Island (South Shetland Archipelago) in the austral summer 2018/2019 clearly indicate the importance of large-scale transport in shaping the level of pollution in areas very distant from potential sources of contamination. Additionally, radioisotope pollution can be measured even after a very long period (>60 years) since their occurrence.

Mercury fractionation - Problems in method application.

Mercury (Hg) is a global pollutant with a negative effect on human and ecosystem health. Mercury is toxic in all forms. The toxicity, however, varies depending on the form of mercury, determining its physical and chemical properties.

Mercury in the Polish part of the Baltic Sea: A response to decreased atmospheric deposition and changing environment.

Our review of the literature showed that since the beginning of the socio-economic transformation in Poland in the 1990s, the downward trend in Hg emissions and its deposition in the southern Baltic Sea was followed by a simultaneous decrease in Hg levels in water and marine plants and animals. Hg concentrations in the biota lowered to values that pose no or low risk to wildlife and seafood consumers. However, in the first decade of the current century, a divergence between these two trends became apparent and Hg concentrations in fish, herring and cod, began to rise.

Mercury concentration and speciation in benthic organisms from Isfjorden, Svalbard.

Polar regions are an important part of the global mercury cycle and interesting study sites due to different possible mercury sources. The full understanding of mercury transformations in the Arctic is difficult because this region is the systems in transition -where the effects of the global climate change are the most prominent. Benthic organisms can be valuable bioindicators of heavy metal contamination.

Status and trends of mercury pollution of the atmosphere and terrestrial ecosystems in Poland.

The goal of this paper is to assess the current status and trends of total mercury (THg) contamination of the atmosphere and terrestrial ecosystems in Poland. The study shows that the reduced domestic and worldwide atmospheric emission of Hg resulted in decreased THg level in the terrestrial biotope and biosphere. Considering that Poland is one of the main Hg emitters in Europe, the THg concentrations in its abiotic environment are still elevated.

Alimentary exposure and elimination routes of rare earth elements (REE) in marine mammals from the Baltic Sea and Antarctic coast.

Marine mammals found at the top of the trophic pyramid are excellent bioindicators of pollutants in the marine environment, the concentrations of which increase along with the trophic level of the organism. As these animals are usually protected species, their contamination has to be assessed non-invasively by analysing excrement and epidermal structures such as fur or claws. The present study involved testing the excrement and fur of the grey seal (Halichoerus grypus) from the Southern Baltic coast and the Southern elephant seal (Mirounga leonine) from Admiralty Bay, along with fish muscle (food) and the lithological background of both areas, for the presence of rare earth elements (REE).

Anthropogenic radioactive isotopes in Actiniaria from the Svalbard archipelago.

The abundance of radionuclides in the Arctic Actiniaria has limited study despite their environmental importance in coastal food chains. Although the Arctic has incurred relatively little contamination by anthropogenic radionuclides as a result of nuclear weapons tests, there are still detectable levels of radionuclide activity observed in marine species. In this study of anthropogenic radionuclide activity in Actiniaria from Spitsbergen we observed levels of Sr from 0.

Meteorological phenomenon as a key factor controlling variability of labile particulate mercury in rivers and its inflow into coastal zone of the sea.

Mercury (Hg) is recognized as a global pollutant, which can be transported to the sea by suspended particulate matter (SPM) via rivers constituting the main source of mercury in the southern Baltic sea. The aim of the present study was to characterize the mercury fractions in suspended particulate matter, as well as the transformations of Hg during its riverine transportation into the sea. The thermo-desorption method was used to determine the labile and stable mercury fractions in SPM of rivers (Reda, Zagórska Struga, Gizdepka, Płutnica) within the Baltic Sea basin.

Fur and faeces - Routes of mercury elimination in the Baltic grey seal (Halichoerus grypus grypus).

This study focused on evaluating the elimination of Hg by Baltic grey seals (Halichoerus grypus grypus) via faeces and pelage. In addition, we investigated the potential for ecosystem contamination via these routes. Faeces and fur were collected in 2014-2017 from captive adult grey seals and their pups.

Mobility of mercury in soil and its transport into the sea.

Mercury (Hg) is deposited temporarily in soil and can be remobilised into rivers and seas. Given that rivers are a significant part of the mercury budget in the southern Baltic region (inland sea located in northern Europe) and meteorological changes (e.g.

Temporal changes in the content of labile and stabile mercury forms in soil and their inflow to the southern Baltic Sea.

Rivers represent the main source of mercury (Hg) in the Southern Baltic. Nevertheless, the concentration and proportion of individual Hg forms in rivers depend on the management of the river basin, as well as on the intensity of meteorological phenomena. Hence the aim of the present study was to determine the influence of drought and rains/intense rains on the content of labile and stable Hg forms in the soil of river catchments with various types of land management, and on the inflow of bioavailable mercury to the coastal zone of the sea.

Impact of hydrotechnical works on outflow of mercury from the riparian zone to a river and input to the sea.

The aim of this research was to assess the impact of hydrotechnical works within the riverbed and riparian zone on the mobility of mercury in soil and its outflow to the river and the sea. Deepening and reconstruction of the riverbed or the cutting of reeds, influenced the fate of mercury in the river system. However, only activitis that disturbed the riperian zone increased mobilization of Hg in soils.

Changes in total mercury, methylmercury, and selenium blood levels during different life history stages of the Baltic grey seal (Halichoerus grypus grypus).

Using the blood of grey seal pups, the blood and milk of female grey seals inhabiting the Hel Marine Station of Gdansk University's Institute of Oceanography (HMS), we monitored the transfer of total mercury (THg), methylmercury (MeHg), and selenium (Se) with blood during foetal life and nursing. Changes in the concentration of mercury and selenium were characterised in the pups' blood during their first three months of life when they transition from suckling, to a post-weaning fast, to eating fish. In the blood of pregnant females, there was a significant decrease in THg and MeHg concentrations throughout the gestation, indicating the transfer of these toxins through the placenta into the foetus.

Cs and K in gray seals Halichoerus grypus in the southern Baltic Sea.

This study presents levels of Cs and K concentrations in the placentas of seals gathered in the period 2007-2015. The mean activity of Cs and K was 5.49 Bq kgw.

The effect of land use in the catchment and meteorological conditions on the riverine transport of dissolved organic carbon into the Puck Lagoon (southern Baltic).

Dissolved organic carbon (DOC) concentration and fluxes from four rivers draining the catchment of the Puck Lagoon in southern Baltic are presented. Water samples from rivers and coastal zone close to the rivers' mouth were collected from April 2015 to March 2017. DOC was measured using high temperature catalytic oxidation with an NDIR detection.

Coastal erosion-a "new" land-based source of labile mercury to the marine environment.

Mercury (Hg) can be introduced into the marine environment in many different ways. In the case of the Baltic Sea, rivers and atmospheric deposition are the predominant ones. However, in the face of ongoing climate change, a new potential source, coastal erosion, is starting to become more important and is currently considered to be the third largest source of Hg in the Gdansk Basin region.

Mercury fractionation in marine macrofauna using thermodesorption technique: Method and its application.

Mercury (Hg) is one of the most dangerous elements, and its toxicity and ability to accumulate in organisms depend on its chemical form. There are numerous methods of Hg speciation analysis, out of which the least expensive and the least time-consuming one is thermodesorption. The method has been successfully used for the analysis of abiotic samples - soils and sediments.

Watershed characteristics and climate factors effect on the temporal variability of mercury in the southern Baltic Sea rivers.

Mercury (Hg) is a neurotoxic metal which can enter into the human organism mainly by fish consumption, skin and transpiration. In the coastal zone of the southern Baltic Sea, rivers are the main source of Hg. The Polish region represents the largest proportion of the Baltic Sea catchment and this research included four rivers of the Baltic watershed: the Reda, Zagórska Struga, Kacza and Gizdepka.