Design and optimization of sensitive analytical spectrophotometric method for micro determination of copper(II) from e-waste by using of novel chromogenic extractant.

In this article, a novel spectrophotometric reagent 1-(pyrimidine)-4, 4, 6-trimethyl-1,4-dihydropyrimidine-2-thiol [PTPT] has been synthesized for liquid-liquid extraction and spectrophotometric determination of copper(II). The as-synthesized ligand has been selectively forms stable complex with copper(II) in basic medium (pH 9.0), in presence of mild pyridine the extraction and color stability has found to be synergistically enhanced.