Int J Environ Res Public Health
September 2024
The proportion of older adults is increasing globally, yet many of them experience food insecurity. Technological innovations, such as increased access to internet- and mobile-based food delivery apps (FDAs), may help mitigate food insecurity. However, this topic has been understudied.
View Article and Find Full Text PDFBiochar has proven effective in the remediation of excess nitrogen from soil and water. Excess nitrogen from agricultural fields ends up in aquatic systems and leads to reduced water quality and the proliferation of invasive species. This study aimed to assess the efficiency of chemically surface-modified biochar produced from invasive L.
View Article and Find Full Text PDFMalalignment in the lower limb structure occurs due to various causes. Accurately evaluating limb alignment in situations where malalignment needs correction is necessary. To create an automated support system to evaluate lower limb alignment by quantifying mechanical tibiofemoral angle (mTFA), mechanical lateral distal femoral angle (mLDFA), medial proximal tibial angle (MPTA), and joint line convergence angle (JLCA) on full-length weight-bearing radiographs of both lower extremities.
View Article and Find Full Text PDFGlobally, water scarcity in arid and semiarid regions has become one of the critical issues that hinder sustainable agriculture. Agriculture, being a major water consumer, presents several challenges that affect water availability. Hydrogels derived from polysaccharides seed gums are hydrophilic polymers capable of retaining substantial moisture in their three-dimensional network and releasing it back into the soil during drought conditions.
View Article and Find Full Text PDFPhenoxyacetic acid herbicides are widely used in agriculture for controlling weeds. These organic compounds are persistent and recalcitrant, often contaminating water and soil. Therefore, we studied five pristine biochars (BCs), and southern yellow pine (SYP) based self-activated carbon (SAC) for the adsorptive removal of 2,4-Dichlorophenoxyacetic acid (2,4-D) herbicide.
View Article and Find Full Text PDFThis research presents a novel and environmentally friendly approach for the synthesis of multifunctional nanobiocomposites for the efficient removal of toxic heavy metal and dye, as well as the disinfection of wastewater microorganisms. The nanobiocomposites (KAC-CS-AgNPs) were prepared by incorporating photochemically generated silver nanoparticles (AgNPs) within a chitosan (CS)-modified, high-surface-area activated carbon derived from kenaf (KAC), using a unique self-activation method. The even distribution of AgNPs was visible in the scanning electron microscopy images and a Fourier transform infra red study demonstrated major absorption peaks.
View Article and Find Full Text PDFInt J Biol Macromol
January 2023
Rapid population growth and the resultant pollution of freshwater resources have created a water stress condition reducing the availability of safe and affordable water. Guar gum, a biocompatible macromolecule obtained from the endosperm of the seeds of Cyamopsis tetragonolobus, is a fascinating raw material for multifunctional adsorbents. This review assembled the work conducted by various researchers over the past few decades and discussed the structure, properties, and different modifications methods employed to develop versatile guar gum-based adsorbent.
View Article and Find Full Text PDFA mix proportion of off-spec fly ash (FA)-added, seawater-mixed pervious concrete (SMPC) was optimized for compressive strength and permeability and then the optimized SMPC was tested for the rate and extent of aqueous phosphorus removal. An optimum mix proportion was obtained to attain the percentages (% wt.) of FA-to-binder at 15.
View Article and Find Full Text PDFPervious concrete mix was optimized for the maximum compressive strength and the desired permeability at 7 mm/s with varying percentages of water-to-binder (W/B), fly ash-to-binder (FA/B), nano-iron oxide-to-binder (NI/B) and water reducer-to-binder (WR/B). The mass ratio of coarse aggregates in sizes of 4.75-9.
View Article and Find Full Text PDFNanotechnology and its application is one of the rapidly developing sciences. As demand of fresh drinking water is increasing, nanotechnology can contribute noticeable development and improvement to water treatment process. Disinfection process is the last and most important step in water and wastewater treatment process.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
January 2013
Waste materials containing Di-(2-ethylhexyl) phthalate (DEHP), a suspected endocrine disruptor and reasonably anticipated human carcinogen, are typically disposed of in landfills. Despite this, very few studies had been conducted to isolate and identify DEHP-degrading bacteria in landfill leachate. Therefore, this study was conducted to isolate and characterize bacteria in landfill leachate growing on DEHP as the sole carbon source and deteriorating PVC materials.
View Article and Find Full Text PDFInt Biodeterior Biodegradation
April 2012
Newly isolated, not previously reported, di-(2-ethylhexyl) phthalate (DEHP)-degraders were augmented to assess their role in polyvinyl chloride (PVC) shower curtain deterioration and DEHP leaching. The biofilms that developed on the surfaces of the bioaugmented shower curtains with Gram-positive strains LHM1 and LHM2 were thicker than those of the biostimulated and Gram-negative strain LHM3-augmented shower curtains. The first derivative thermogravimetric (DTG) peaks of the bioaugmented shower curtains with the Gram-positive bacteria were observed at ~287°C, whereas the control and Gram-negative strain LHM3-augmented shower curtains were detected at ~283°C.
View Article and Find Full Text PDFThis study was conducted to evaluate the effect of commercially available engineered iron oxide nanoparticles coated with a surfactant (ENP(Fe-surf)) on effluent water quality from a lab-scale sequencing batch reactor as a model secondary biological wastewater treatment. Results showed that ~8.7% of ENP(Fe-surf) applied were present in the effluent stream.
View Article and Find Full Text PDFIn Fenton-driven oxidation treatment systems, reaction intermediates derived from parent compounds can play a significant role in the overall treatment process. Fenton-like reactions in the presence of toluene or benzene, involved a transformation mechanism that was highly efficient relative to the conventional Fenton-driven mechanism. A delay in hydrogen peroxide (H2O2) reaction occurred until the complete or near-complete transformation of toluene or benzene and involved the simultaneous reaction of dissolved oxygen.
View Article and Find Full Text PDFFenton-driven regeneration of methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC) involves an Fe amendment step to increase the Fe content and to enhance the extent of MTBE oxidation and GAC regeneration. Four forms of iron (ferric sulfate, ferric chloride, ferric nitrate, ferrous sulfate) were amended separately to GAC. Following Fe amendment, MTBE was adsorbed to the GAC followed by multiple applications of H2O2.
View Article and Find Full Text PDFFenton-driven oxidation of methyl tert-butyl ether (MTBE) (0.11-0.16mM) in batch reactors containing ferric iron (5mM) and hydrogen peroxide (H(2)O(2)) (6mM) (pH=3) was performed to investigate MTBE transformation mechanisms.
View Article and Find Full Text PDFThis study was conducted to assess the applicability of alkaline hydrolysis as an alternative ex situ technology for remediating 2,4,6-trinitrotoluene (TNT)-contaminated water. TNT reactivity had a strong dependence on the reaction pH (11-12) and initial TNT (5-25 mg L(-1)) in batch systems, resulting in pseudo first-order transformation rate, k ranging between 1.9 x 10(-3) and 9.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
June 2005
Laboratory batch sorption experiments were conducted to investigate the impact of hydrogen peroxide (H2O2) pre-application on post-sorptive behavior of 2,4,6-trinitrotoluene (TNT) in different natural soils (average soil, high Fe soil, and high pH soil). After H2O2 application, the values of Freundlich coefficient Kf were increased by approximately 160% for the average and high pH soils and by approximately 120% for the high Fe soil, showing that the soils became more favorable for TNT sorption after H202 application. Nonlinearity in terms of the Freundlich exponent n was increased by approximately 40% for the average and high pH soils and by approximately 30% for the high Fe soil, showing greater sorption affinity of TNT for the oxidized soils at lower TNT concentrations and also implying greater TNT availability for transport at high concentrations.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
June 2004
The hypothesis evaluated was that sorption/desorption experiments conducted under nonequilibrium conditions would sorb/desorb smaller amounts of polycyclic aromatic hydrocarbons (PAHs) in comparison to those conducted under an equilibrium condition. The magnitude of phenanthrene's (PHEs) sorption coefficient was approximately the same for both equilibrium and nonequilibrium conditions. However, when the initial PHE concentrations were varied, sorption nonequilibrium resulted in a 1.
View Article and Find Full Text PDFEffects of H(2)O(2) dosage (0, 10, 50, 100 and 300 mg/l), reaction pH (11.9, 6.5 and 2.
View Article and Find Full Text PDFThis study was conducted to evaluate the influence of sorbent modification by synthetic, chemical/thermal weathering on the sorptive behavior of polycyclic aromatic hydrocarbons (PAHs). A clean sandy-clay-loam soil was subjected to Soxhlet extraction and PAH sorptive phenomena were evaluated based on quantity and quality changes in soil organic matter (SOM) and clay minerals. Critical changes in sorption capacity were found to depend on the initial PAH concentrations.
View Article and Find Full Text PDFDesorption and biodegradation of pyrene (PYR) were investigated and their relationships to soil characteristics were addressed. The results indicated that maximum achievable desorption was 30.2, 10.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
October 2003
Pyrene and phenanthrene degradation was examined in both single and binary slurry systems for three different natural soils. It was found that the amount of total expandable clays (smectite and vermiculite) was in a good agreement with the achieved rate and extent of biodegradation. For instance, the intrinsic phenanthrene biodegradation rate was 626 microg/L/day for the soil with the largest expandable clay and 3203 microg/L/day for the soil with the least.
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