Publications by authors named "Sangaraju Sambasivam"

Phase-pure crystalline chalcostibite (CuSbS) thin films were prepared by depositing Cu/Sb/Cu metal stacks using a thermal evaporation method, followed by sulfurization at 400  C and 430  C for different durations. The investigation revealed the formation of a dominant orthorhombic CuSbS phase accompanied by a minor SbS phase in the film stacks sulfurized at 400  C for 10-60 min. Extending the reaction time to 90 min triggered a decrease in the SbS phase and the emergence of an additional famatinite (CuSbS) phase alongside the dominant CuSbS phase.

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TiCT has attracted considerable attention from researchers in energy storage due to its unique structure and beneficial surface functional group characteristics. Recent studies have focused extensively on developing TiCT composites to create potential electrode materials for energy storage applications. Carbon nanofiber is often combined with TiCT to produce high-performance functional nanocomposites, effectively harnessing the unique properties of TiCT nanosheets while ensuring exceptional electrochemical behavior.

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This paper presents a comprehensive overview of the potential applications for Photo-Acoustic (PA) imaging employing functional nanoparticles. The exploration begins with an introduction to nanotechnology and nanomaterials, highlighting the advancements in these fields and their crucial role in shaping the future. A detailed discussion of the various types of nanomaterials and their functional properties sets the stage for a thorough examination of the fundamentals of the PA effect.

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In this present work, the preparation of ternary MoS-NiO-CuO nanohybrid by a facile hydrothermal process for photocatalytic and photovoltaic performance is presented. The prepared nanomaterials were confirmed by physio-chemical characterization. The nanosphere morphology was confirmed by electron microscopy techniques for the MoS-NiO-CuO nanohybrid.

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In this study, the fruit of Terminalia chebula, commonly known as chebulic myrobalan, is used as the precursor for carbon for its application in supercapacitors. The Terminalia chebula biomass-derived sponge-like porous carbon (TC-SPC) is synthesized using a facile and economical method of pyrolysis. TC-SPC thus obtained is subjected to XRD, FESEM, TEM, HRTEM, XPS, Raman spectroscopy, ATR-FTIR, and nitrogen adsorption-desorption analyses for their structural and chemical composition.

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Biopolymer-derived polyelectrolyte complexes (PECs) are a class of materials that have emerged as promising candidates for developing advanced electrochemical sensors due to their tunable properties, biocompatibility, cost-effective production, and high surface area. PECs are formed by combining positively and negatively charged polymers, resulting in a network with intriguing properties that can be tailored for specific sensing applications. The resultant PECs-based nanocomposites were used to modify the glassy carbon electrode (GCE) to detect the sulfamethazine (SFZ) antibiotic drug.

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Chromium is a multivalent metal with great development in the energy storage field because it can effectively improve the electrochemical performance of the material. However, chromium(VI) is soluble in water and toxic, which causes serious metal pollution in the environment. In addition, nanoplastics are difficult to degrade and easy to accumulate, which is an urgent environmental problem to be solved.

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The accelerated development of special-wetting polymeric materials with hierarchical pores for membrane applications is crucial to effectively separating water-soluble and insoluble pollutants, such as oily wastewater, emulsion, organic pollutants, and heavy metals. This pressing environmental and socioeconomic issue requires the implementation of effective remediation technologies. In this study, we successfully fabricated an environmentally friendly membrane with a flexible property by combining biopolymers and magnetic nanohybrids of iron oxide (FeO)-doped tungsten oxide (WO) through a thermal-induced phase separation process (TIPS).

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Hierarchical nanostructures have harvested noteworthy attention lately owing to their remarkable capabilities in the fields of energy storing and transformation, catalysis, and electrical devices. We established an effort less and template-free synthetic method to create hierarchical hetero nanostructures of ZnVO, taking into account the benefits of hierarchical nanostructures, we investigated the performance of HNs (Hierarchical Nanostructures) as electrochemical supercapacitors. Electrochemical tests were tested in a 6 M KOH solution to assess their capabilities.

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With the depletion of fossil fuels and growing environmental concerns, the modernized era of technology is in desperate need of sustainable and eco-friendly materials. The industrial sector surely has enough resources to produce cost-effective, renewable, reusable, and sustainable raw materials. The family of very porous solid materials known as aerogels has a variety of exceptional qualities, such as high porosity, high specific surface area, ultralow density, and superior thermal, acoustic, and dielectric properties.

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Herein, we synthesized a CdSe quantum dots (QDs)-decorated ternary metal oxide nanocomposite of ZnO/TiO/CuO through a simple hydrothermal method. The prepared nanocomposite exhibited monoclinic, hexagonal, and cubic phase structures in XRD (X-ray diffraction) analysis. UV-vis absorbance spectra showed the broad absorption spectrum.

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Over the past few years, transition metal carbides, nitrides, and carbonitrides, commonly referred to as MXenes have been discovered and utilized quickly in a range of technical fields due to their distinctive and controlled characteristics. MXenes are a new class of two-dimensional (2D) materials that have found extensive use in a variety of fields, including energy storage, catalysis, sensing, biology, and other scientific disciplines. This is because of their exceptional mechanical and structural characteristics, metal electrical conductivity, and other outstanding physical and chemical properties.

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Here, a simple one-step hydrothermal-assisted carbonization process was adopted for the preparation of nitrogen/phosphorous-doped carbon dots from a water-soluble polymer, poly 2-(methacryloyloxy)ethyl phosphorylcholine (PMPC). By the free-radical polymerization method, PMPC was synthesized using 2-(methacryloyloxy)ethyl phosphorylcholine (MPC) and 4,4'-azobis (4-cyanovaleric acid). The water-soluble polymers, PMPC, that have nitrogen/phosphorus moieties are used to prepare carbon dots (P-CDs).

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Chebulic Myrobalan is the main ingredient in the Ayurvedic formulation Triphala, which is used for kidney and liver dysfunctions. Herein, natural nitrogen-doped carbon dots (NN-CDs) were prepared from the hydrothermal carbonization of Chebulic Myrobalan and were demonstrated to sense heavy metal ions in an aqueous medium. Briefly, the NN-CDs were developed from Chebulic Myrobalan by a single-step hydrothermal carbonization approach under a mild temperature (200 °C) without any capping and passivation agents.

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In this study, sustainable, low-cost, and environmentally friendly biomass () was employed as a precursor for the formation of nitrogen-doped carbon dots (N-CDs). The hydrothermally assisted fruit-derived N-CDs (TC-CDs) emitted different bright fluorescent colors under various excitation wavelengths. The prepared TC-CDs showed a spherical morphology with a narrow size distribution and excellent water dispensability due to their abundant functionalities, such as oxygen- and nitrogen-bearing molecules on the surfaces of the TC-CDs.

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Supercapacitors (SCs), also known as ultracapacitors, should be one of the most promising contenders for meeting the needs of human viable growth owing to their advantages: for example, excellent capacitance and rate efficiency, extended durability, and cheap materials price. Supercapacitor research on electrode materials is significant because it plays a vital part in the performance of SCs. Polyaniline (PANI) is an exceptional candidate for energy-storage applications owing to its tunable structure, multiple oxidation/reduction reactions, cheap price, environmental stability, and ease of handling.

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Just over a decade, perovskite solar cells (PSCs) have been emerged as a next-generation photovoltaic technology due to their skyrocketing power conversion efficiency (PCE), low cost, and easy manufacturing techniques compared to Si solar cells. Several methods and procedures have been developed to fabricate high-quality perovskite films to improve the scalability and commercialize PSCs. Recently, several printing technologies such as blade-coating, slot-die coating, spray coating, flexographic printing, gravure printing, screen printing, and inkjet printing have been found to be very effective in controlling film formation and improving the PCE of over 21%.

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In this research literature, a tungsten disulfide/iron cobaltite (WS/FeCoO) interwoven construction array was prepared by a simplistic hydrothermal approach on Ni foam as an integrative electrode for supercapacitors (SCs). For characterization of the wearing of WS nanostructure on FeCoO nanosheets (WS/FeCoO) by the Scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The WS/FeCoO nanosheets supply a larger surface region and sufficient space to allow for volume changes.

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Over the past few decades, the application of new novel materials in energy storage system has seen excellent development. We report a novel MnCoO/NiO nanostructure prepared by a simplistic chemical bath deposition method and employed it as a binder free electrode in the supercapacitor. The synergistic attraction from a high density of active sites, better transportation of ion diffusion and super-most electrical transportation, which deliver boost electrochemical activities.

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Magnetite (FeO) nanoparticles were synthesized using the chemical coprecipitation method. Several nanoparticle samples were synthesized by varying the concentration of iron salt precursors in the solution for the synthesis. Two batches of nanoparticles with average sizes of 10.

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Quantum dot sensitized solar cell (QDSSC) performance is primarily limited by the recombination of charges at the interfaces of TiO/quantum dot (QD) sensitizer/electrolyte. Hence, blocking or suppressing the charge recombination is an essential requirement to elevate the QDSSC performance to the next level. To retard the charge recombination, herein, we propose the introduction of a SnO nanograss (NG) interlayer on the surface of TiO using the facile chemical bath deposition method.

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Porous carbon nanofibers codoped with nitrogen and sulfur (NFs) were prepared by pyrolysis of trithiocyanuric acid, silica nanospheres and polyacrylonitrile (PAN) followed by electrospinning. The NFs were used to modify a glassy carbon electrode (GCE) which then displayed highly sensitive response to traces of Cd(II). Compared to a bare GCE and a Nafion modified GCE, the GCE modified with codoped NFs shows improved sensitivity for Cd(II) in differential pulse anodic sweep voltammetry.

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