Influence of Structural Disorders on the Tribological Behavior of Phosphate-Intercalated Layered Double Hydroxide Additives in Polyalphaolefin.

In this work, several phosphate-intercalated Mg-Al layered double hydroxides (LDHs) were synthesized and evaluated as solid lubricant additives in polyalphaolefin (PAO-4) by means of tribotesting on coupled GCr15/cast iron contacts. The effects of test parameters such as normal loads, additive concentrations, and substrate surface roughness were investigated, while the LDH crystal structure received considerable attention. Several types of structural disorder after anion exchange were identified based on X-ray diffraction (XRD) analysis.