C[double bond, length as m-dash]N linked covalent organic framework for the efficient adsorption of iodine in vapor and solution.

Volatile nuclear wastes, such as iodine, have received worldwide attention because it poses risks to public safety and pollutes the environment. The efficient capture of radioactive iodine is of vital importance for the safe utilization of nuclear power. Herein, we report a series of stable covalent organic framework (COF) materials with high efficiency to capture radioactive iodine species.

Theoretical Screening and Experimental Synthesis of Ultrahigh-Iodine Capture Covalent Organic Frameworks.

Radioactive materials of nuclear waste would be hazardous to human health such as the reproductive and metabolic system. How to design a radioactive material adsorbent quickly and efficiently is still a great challenge. In this study, a strategy for the efficient design of a high-potential radioactive iodine uptake adsorbent by theoretical screening is proposed.

Easily Constructed Imine-Bonded COFs for Iodine Capture at Ambient Temperature.

Volatile radionuclides generated during the nuclear fission process, such as iodine, pose risks to public safety and cause the threat of environmental pollution. Covalent organic framework (COF) materials have a controlled pore structure and a large specific surface area and thus demonstrate great opportunities in the field of radioactive iodine adsorption. However, the harsh synthetic conditions and the weak binding capability toward iodine have significantly restricted the applications of COFs in iodine adsorption.