Crystal Structure and Spectroscopic and Magnetic Properties of the Manganese(II) and Copper(II) Azido-Tetramethylammonium Systems.

The compounds [N(CH(3))(4)][Cu(N(3))(3)] (1) and [N(CH(3))(4)][Mn(N(3))(3)] (2) have been synthesized and characterized. Compound 1 crystallizes in the monoclinic P2(1)/n space group, with Z = 4, a = 7.473(2) Å, b = 15.