Publications by authors named "Samuel R Wolfe"
Eur J Inorg Chem
December 2017
Article Synopsis
- Redox-active ligands like arylazothioformamide (ATF) complicate the determination of oxidation states for both the ligands and metal centers due to their three distinct oxidation states.
- ATF's interaction with metals leads to significant color changes, making it useful for detecting and separating metals.
- The study utilizes X-ray crystallography and computational modeling to clarify the oxidation states in ATF-metal complexes, finding that complexes from zerovalent metals contain dicationic metal centers with singly reduced ATF, while using Cu(I) maintains both the metal's oxidation state and the ligand's neutral form.
